The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Trimetallic Oxyhydroxide Coralloids for Efficient Oxygen Evolution Electrocatalysis
Abstract
Trimetallic oxyhydroxides are one of the most effective materials for oxygen evolution reaction (OER) catalysis, a key process for water splitting. Herein, we describe a facile wet‐chemical method to directly grow a series of coralloid trimetallic oxyhydroxides on arbitrary substrates such as nickel foam (NF) and carbon nanotubes (CNTs). The amount of iron in these oxyhydroxide sponges on NF and CNTs was precisely controlled, revealing that the electrocatalytic activity of the WCoFe trimetallic oxyhydroxides depends on the Fe amount in a volcano‐like fashion. The optimized W 0.5 Co 0.4 Fe 0.1/NF catalyst exhibited an overpotential of only 310 mV to deliver a large current density of 100 mA cm−2 and a very low Tafel slope of 32 mV dec−1. It also showed superior stability with negligible activity decay after use in the OER for 21 days (>500 h). X‐ray photoelectron spectroscopy revealed that the addition of Fe leads to an on average lower Co oxidation state, which contributes to the enhanced OER performance.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Homogeneously dispersed multimetal oxygen-evolving catalysts
Zhang, B., Zheng, X., Voznyy, O., Comin, R., Bajdich, M., García-Melchor, M., Han, L., Xu, J., Liu, M., Zheng, L., et al. (2016) · Science · doi:10.1126/science.aaf1525 · Cited by 2,447
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Peng, Z., Jia, D., Al‐Enizi, A. M., Elzatahry, A. A., & Zheng, G. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201402031 · Cited by 494
Wu, Y., Cai, S., Wang, D., He, W., & Li, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302606d · Cited by 351
Kuang, Y., Feng, G., Li, P., Bi, Y., Li, Y., & Sun, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509616 · Cited by 259
Cited by
A review on fundamentals for designing oxygen evolution electrocatalysts
Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936
Ye, S., Shi, Z., Feng, J., Tong, Y., & Li, G. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712549 · Cited by 561
Self-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Trimetallic Spinel NiCo2−xFexO4 Nanoboxes for Highly Efficient Electrocatalytic Oxygen Evolution
Huang, Y., Zhang, S. L., Lu, X. F., Wu, Z., Luan, D., & Lou, X. W. (. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103058 · Cited by 380
Jin, Y., Huang, S., Yue, X., Du, H., & Shen, P. K. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04226 · Cited by 359
Metadata
- Authors
- Pi, Y., Shao, Q., Wang, P., Lv, F., Guo, S., Guo, J., & Huang, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-03-21
- Volume
- 56
- Issue
- 16
- Pages
- 4502-4506
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2600967916
- Cited by
- 259
- References
- 7
- FWCI
- 10.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pi, Y., Shao, Q., Wang, P., Lv, F., Guo, S., Guo, J., & Huang, X. (2017). Trimetallic Oxyhydroxide Coralloids for Efficient Oxygen Evolution Electrocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201701533
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