The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Cooperative Light‐Activated Iodine and Photoredox Catalysis for the Amination of C−H Bonds
Open accessAbstract
An unprecedented method that makes use of the cooperative interplay between molecular iodine and photoredox catalysis has been developed for dual light‐activated intramolecular benzylic C−H amination. Iodine serves as the catalyst for the formation of a new C−N bond by activating a remote C −H bond (1,5‐HAT process) under visible‐light irradiation while the organic photoredox catalyst TPT effects the reoxidation of the molecular iodine catalyst. To explain the compatibility of the two involved photochemical steps, the key N−I bond activation was elucidated by computational methods. The new cooperative catalysis has important implications for the combination of non‐metallic main‐group catalysis with photocatalysis.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Photoredox-Catalyzed C–H Functionalization Reactions
Holmberg-Douglas, N., & Nicewicz, D. A. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00311 · Cited by 989
Photocatalytic Late-Stage C–H Functionalization
Bellotti, P., Huang, H.-M., Faber, T., & Glorius, F. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00478 · Cited by 623
Motiwala, H. F., Armaly, A. M., Cacioppo, J. G., Coombs, T. C., Koehn, K. R. K., Norwood, V. M., & Aubé, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00749 · Cited by 593
Guo, W., Wang, Q., & Zhu, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00774a · Cited by 423
Hu, A., Guo, J.-J., Pan, H., Tang, H., Gao, Z., & Zuo, Z. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13131 · Cited by 384
Metadata
- Authors
- Becker, P., Duhamel, T., Stein, C. J., Reiher, M., & Muñiz, K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-06
- Volume
- 56
- Issue
- 27
- Pages
- 8004-8008
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2620813024
- Cited by
- 200
- References
- 1
- FWCI
- 13.05
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Becker, P., Duhamel, T., Stein, C. J., Reiher, M., & Muñiz, K. (2017). Cooperative Light‐Activated Iodine and Photoredox Catalysis for the Amination of C−H Bonds. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201703611
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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