The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Exclusive Formation of Formic Acid from CO2 Electroreduction by a Tunable Pd‐Sn Alloy
Abstract
Conversion of carbon dioxide (CO 2) into fuels and chemicals by electroreduction has attracted significant interest, although it suffers from a large overpotential and low selectivity. A Pd‐Sn alloy electrocatalyst was developed for the exclusive conversion of CO 2 into formic acid in an aqueous solution. This catalyst showed a nearly perfect faradaic efficiency toward formic acid formation at the very low overpotential of −0.26 V, where both CO formation and hydrogen evolution were completely suppressed. Density functional theory (DFT) calculations suggested that the formation of the key reaction intermediate HCOO* as well as the product formic acid was the most favorable over the Pd‐Sn alloy catalyst surface with an atomic composition of PdSnO 2, consistent with experiments.
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Cites
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Cited by
Electrocatalytic Alloys for CO2 Reduction
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Role of oxygen-bound reaction intermediates in selective electrochemical CO 2 reduction
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Ternary Sn‐Ti‐O Electrocatalyst Boosts the Stability and Energy Efficiency of CO2 Reduction
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Catholyte‐Free Electrocatalytic CO2 Reduction to Formate
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Metadata
- Authors
- Bai, X., Chen, W., Zhao, C., Li, S., Song, Y., Ge, R., Wei, W., & Sun, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-08-24
- Volume
- 56
- Issue
- 40
- Pages
- 12219-12223
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2736832726
- Cited by
- 328
- References
- 35
- FWCI
- 9.96
- Type
- journal article
- Language
- en
- Open access
- closed
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