Nanostructured Materials for Heterogeneous Electrocatalytic CO2 Reduction and their Related Reaction Mechanisms
Abstract
The gradually increased concentration of carbon dioxide (CO 2) in the atmosphere has been recognized as the primary culprit for the rise of the global mean temperature. In recent years, development of routes for highly efficient conversion of CO 2 has received much attention. This Review describes recent progress on the design and synthesis of solid‐state catalysts for the electrochemical reduction of CO 2. The significance of this catalytic conversion is presented, followed by the general parameters for CO 2 electroreduction and a summary of the reaction apparatus. We also discuss various types of solid catalysts based on their CO 2 conversion mechanisms. We summarize the crucial factors (particle size, surface structure, composition, etc.) determining the performance for electroreduction.
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Gao et al. reported a partially oxidized Co 4 atomic layer catalyst that achieved FEHCOO- up to 90% at -0.24 V vs RHE for over 40 hours.
“Gao et al. reported a partially oxidized Co 4atomic layer catalyst that achieved FEHCOO -up to 90% at -0.24 V vs RHE for over 40 hours.[72]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [72]
The Tafel slope of 44 mV dec-1 suggested the enhanced CO2 adsorption capability of the layered catalyst accelerated CO2 activation.
“The Tafel slope of 44 mV dec -1 suggested the enhanced CO2 adsorption capability of the layered catalyst accelerated CO2 activation.”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [72]
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The Role of Adsorbed CN and Cl on an Au Electrode for Electrochemical CO<sub>2</sub> Reduction
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Electronic Tuning of Co, Ni‐Based Nanostructured (Hydr)oxides for Aqueous Electrocatalysis
Kuang, M., Han, P., Huang, L., Cao, N., Qian, L., & Zheng, G. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201804886 · Cited by 110 · see citing works
Catholyte‐Free Electrocatalytic CO<sub>2</sub> Reduction to Formate
Lee, W., Kim, Y. E., Youn, M. H., Jeong, S. K., & Park, K. T. (2018) · Angewandte Chemie · doi:10.1002/ange.201803501 · Cited by 31 · see citing works
- Authors
- Zhang, L., Zhao, Z., & Gong, J.
- Affiliations
- Tianjin University (CN)
- Corresponding author
- Gong, Jinlong
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-07-26
- Volume
- 56
- Issue
- 38
- Pages
- 11326-11353
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2586675271
- Cited by
- 1,048
- References
- 206
- Citations by year
- 2026: 47 · 2025: 95 · 2024: 120 · 2023: 118 · 2022: 124 · 2021: 143 · 2020: 142 · 2019: 136 · 2018: 106 · 2017: 17
- FWCI
- 4.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (U1463205, 51302185, 21525626, 21606169)
- China Postdoctoral Science Foundation (0401130003)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- electrochemical CO2 reduction, heterogeneous electrocatalysis, nanocatalysts, solid catalysts, reaction mechanism, particle size effects, surface structure, catalyst composition, CO2 conversion
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