The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Surfactant‐Assisted Phase‐Selective Synthesis of New Cobalt MOFs and Their Efficient Electrocatalytic Hydrogen Evolution Reaction
Abstract
Reported herein are two new polymorphic Co‐MOFs (CTGU‐5 and ‐6) that can be selectively crystallized into the pure 2D or 3D net using an anionic or neutral surfactant, respectively. Each polymorph contains a H 2 O molecule, but differs dramatically in its bonding to the framework, which in turn affects the crystal structure and electrocatalytic performance for hydrogen evolution reaction (HER). Both experimental and computational studies find that 2D CTGU‐5 which has coordinates water and more open access to the cobalt site has higher electrocatalytic activity than CTGU‐6 with the lattice water. The integration with co‐catalysts, such as acetylene black (AB) leads to a composite material, AB&CTGU‐5 (1:4) with very efficient HER catalytic properties among reported MOFs. It exhibits superior HER properties including a very positive onset potential of 18 mV, low Tafel slope of 45 mV dec−1, higher exchange current density of 8.6×10−4 A cm−2, and long‐term stability.
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Cites
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CoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction
Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901409 · Cited by 606
Recent progress in metal-organic frameworks-based hydrogels and aerogels and their applications
Wang, L., Xu, H., Gao, J., Yao, J., & Zhang, Q. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213016 · Cited by 594
Recent progress on the long‐term stability of hydrogen evolution reaction electrocatalysts
Zhai, W., Ma, Y., Chen, D., Ho, J. C., Dai, Z., & Qu, Y. (2022) · InfoMat · doi:10.1002/inf2.12357 · Cited by 375
Yan, Y., Li, C., Wu, Y., Gao, J., & Zhang, Q. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta03749d · Cited by 260
Self-citationCoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction
Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie · doi:10.1002/ange.201901409 · Cited by 160
Metadata
- Authors
- Wu, Y., Zhou, W., Zhao, J., Dong, W., Lan, Y., Li, D., Sun, C., & Bu, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-08-18
- Volume
- 56
- Issue
- 42
- Pages
- 13001-13005
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2740838428
- Cited by
- 386
- References
- 10
- FWCI
- 14.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, Y., Zhou, W., Zhao, J., Dong, W., Lan, Y., Li, D., Sun, C., & Bu, X. (2017). Surfactant‐Assisted Phase‐Selective Synthesis of New Cobalt MOFs and Their Efficient Electrocatalytic Hydrogen Evolution Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201707238
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