The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media
Open accessAbstract
Realization of the hydrogen economy relies on effective hydrogen production, storage, and utilization. The slow kinetics of hydrogen evolution and oxidation reaction (HER/HOR) in alkaline media limits many practical applications involving hydrogen generation and utilization, and how to overcome this fundamental limitation remains debatable. Here we present a kinetic study of the HOR on representative catalytic systems in alkaline media. Electrochemical measurements show that the HOR rate of Pt‐Ru/C and Ru/C systems is decoupled to their hydrogen binding energy (HBE), challenging the current prevailing HBE mechanism. The alternative bifunctional mechanism is verified by combined electrochemical and in situ spectroscopic data, which provide convincing evidence for the presence of hydroxy groups on surface Ru sites in the HOR potential region and its key role in promoting the rate‐determining Volmer step. The conclusion presents important references for design and selection of HOR catalysts.
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Cites
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Subbaraman, R., Tripkovic, D., Chang, K.-C., Strmcnik, D., Paulikas, A. P., Hirunsit, P., Chan, M., Greeley, J., Stamenkovic, V., & Markovic, N. M. (2012) · Nature Materials · doi:10.1038/nmat3313 · Cited by 3,053
Surface science studies of model fuel cell electrocatalysts
Markovic, N. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00022-x · Cited by 2,143
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
Sheng, W., Gasteiger, H. A., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483106 · Cited by 1,829
Anion exchange membranes for alkaline fuel cells: A review
Merle, G., Wessling, M., & Nijmeijer, K. (2011) · Journal of Membrane Science · doi:10.1016/j.memsci.2011.04.043 · Cited by 1,695
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
Durst, J., Siebel, A., Simon, C., Hasché, F., Herranz, J., & Gasteiger, H. A. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00440j · Cited by 1,666
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Danilovic, N., van der Vliet, D., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2013) · Nature Chemistry · doi:10.1038/nchem.1574 · Cited by 1,426
Ledezma-Yanez, I., Wallace, W. D. Z., Sebastián-Pascual, P., Climent, V., Feliu, J. M., & Koper, M. T. M. (2017) · Nature Energy · doi:10.1038/nenergy.2017.31 · Cited by 1,285
Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y. (2015) · Nature Communications · doi:10.1038/ncomms6848 · Cited by 1,136
Zheng, J., Sheng, W., Zhuang, Z., Xu, B., & Yan, Y. (2016) · Science Advances · doi:10.1126/sciadv.1501602 · Cited by 863
Cited by
Zheng, Y., Jiao, Y., Vasileff, A., & Qiao, S. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710556 · Cited by 1,489
Li, P., Jiang, Y., Hu, Y., Men, Y., Liu, Y., Cai, W., & Chen, S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00846-8 · Cited by 852
The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum
McCrum, I. T., & Koper, M. T. M. (2020) · Nature Energy · doi:10.1038/s41560-020-00710-8 · Cited by 818
Hydrogen Evolution and Oxidation: Mechanistic Studies and Material Advances
Tian, X., Zhao, P., & Sheng, W. (2019) · Advanced Materials · doi:10.1002/adma.201808066 · Cited by 751
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Metadata
- Authors
- Li, J., Ghoshal, S., Bates, M. K., Miller, T. E., Davies, V., Stavitski, E., Attenkofer, K., Mukerjee, S., Ma, Z., & Jia, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-11-08
- Volume
- 56
- Issue
- 49
- Pages
- 15594-15598
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2765242885
- Cited by
- 304
- References
- 24
- FWCI
- 5.41
- Type
- journal article
- Language
- en
- Open access
- green
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- Li, J., Ghoshal, S., Bates, M. K., Miller, T. E., Davies, V., Stavitski, E., Attenkofer, K., Mukerjee, S., Ma, Z., & Jia, Q. (2017). Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201708484
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