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Covalent Triazine Frameworks via a Low‐Temperature Polycondensation Approach

Open access
Wang, Kewei, Yang, Li‐Ming, Wang, Xi, Guo, Liping, Cheng, Guang, Zhang, Chun, Jin, Shangbin, Tan, Bien, Cooper, Andrew·2017·Angewandte Chemie International Edition

Abstract

Covalent triazine frameworks (CTFs) are normally synthesized by ionothermal methods. The harsh synthetic conditions and associated limited structural diversity do not benefit for further development and practical large‐scale synthesis of CTFs. Herein we report a new strategy to construct CTFs (CTF‐HUSTs) via a polycondensation approach, which allows the synthesis of CTFs under mild conditions from a wide array of building blocks. Interestingly, these CTFs display a layered structure. The CTFs synthesized were also readily scaled up to gram quantities. The CTFs are potential candidates for separations, photocatalysis and for energy storage applications. In particular, CTF‐HUSTs are found to be promising photocatalysts for sacrificial photocatalytic hydrogen evolution with a maximum rate of 2647 μmol h−1 g−1 under visible light. We also applied a pyrolyzed form of CTF‐HUST‐4 as an anode material in a sodium‐ion battery achieving an excellent discharge capacity of 467 mAh g−1.

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Metadata

Authors
Wang, K., Yang, L., Wang, X., Guo, L., Cheng, G., Zhang, C., Jin, S., Tan, B., & Cooper, A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-10-09
Volume
56
Issue
45
Pages
14149-14153
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2755055850
Cited by
639
References
56
FWCI
20.89
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Covalent Triazine Frameworks via a Low‐Temperature Polycondensation Approach. https://app.cochat.ai/papers/10.1002/anie.201708548
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Wang, K., Yang, L., Wang, X., Guo, L., Cheng, G., Zhang, C., Jin, S., Tan, B., & Cooper, A. (2017). Covalent Triazine Frameworks via a Low‐Temperature Polycondensation Approach. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201708548

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