The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Co‐adsorption of Cations as the Cause of the Apparent pH Dependence of Hydrogen Adsorption on a Stepped Platinum Single‐Crystal Electrode
Open accessAbstract
The successful deployment of advanced energy‐conversion systems depends critically on our understanding of the fundamental interactions of the key adsorbed intermediates (hydrogen *H and hydroxyl *OH) at electrified metal–aqueous electrolyte interfaces. The effect of alkali metal cations (Li+, Na+, K+, Cs+) on the non‐Nernstian pH shift of the step‐related voltammetric peak of the Pt(553) electrode is investigated over a wide pH window (1 to 13) by means of experimental and computational methods. The co‐adsorbed alkali cations along the step weaken the OH adsorption at the step sites, causing a positive shift of the potential of the step‐related peak on Pt(553). Density functional calculations explain the observations on the identity and concentration of alkali cations on the non‐Nernstian pH shift, and demonstrate that cation–hydroxyl co‐adsorption causes the apparent pH dependence of “hydrogen” adsorption in the step sites of platinum electrodes.
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Cites
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Ab initio molecular dynamics for liquid metals
Kresse, G., & Hafner, J. (1993) · Physical Review B · doi:10.1103/physrevb.47.558 · Cited by 45,727
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
Momma, K., & Izumi, F. (2011) · Journal of Applied Crystallography · doi:10.1107/s0021889811038970 · Cited by 26,054
Introduction to Solid State Physics
Kittel, C., & Fan, H. Y. (1957) · American Journal of Physics · doi:10.1119/1.1934457 · Cited by 22,240
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1993) · Physical Review B · doi:10.1103/physrevb.48.4978.2 · Cited by 17,144
Surface science studies of model fuel cell electrocatalysts
Markovic, N. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00022-x · Cited by 2,143
Dipole correction for surface supercell calculations
Bengtsson, L. (1999) · Physical Review B · doi:10.1103/physrevb.59.12301 · Cited by 2,052
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
Durst, J., Siebel, A., Simon, C., Hasché, F., Herranz, J., & Gasteiger, H. A. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00440j · Cited by 1,666
Pseudopotentials for high-throughput DFT calculations
Garrity, K. F., Bennett, J. W., Rabe, K. M., & Vanderbilt, D. (2014) · Computational Materials Science · doi:10.1016/j.commatsci.2013.08.053 · Cited by 1,644
Cited by
Zheng, Y., Jiao, Y., Vasileff, A., & Qiao, S. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710556 · Cited by 1,489
Li, P., Jiang, Y., Hu, Y., Men, Y., Liu, Y., Cai, W., & Chen, S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00846-8 · Cited by 852
The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum
McCrum, I. T., & Koper, M. T. M. (2020) · Nature Energy · doi:10.1038/s41560-020-00710-8 · Cited by 818
Self-citationTan, H., Tang, B., Lu, Y., Ji, Q., Lv, L., Duan, H., Li, N., Wang, Y., Feng, S., Li, Z., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-29710-w · Cited by 390
Shah, A. H., Zhang, Z., Huang, Z., Wang, S., Zhong, G., Wan, C., Alexandrova, A. N., Huang, Y., & Duan, X. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00851-x · Cited by 373
Metadata
- Authors
- Chen, X., McCrum, I. T., Schwarz, K. A., Janik, M. J., & Koper, M. T. M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-10-23
- Volume
- 56
- Issue
- 47
- Pages
- 15025-15029
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2763127682
- Cited by
- 336
- References
- 29
- FWCI
- 6.33
- Type
- journal article
- Language
- en
- Open access
- green
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- Chen, X., McCrum, I. T., Schwarz, K. A., Janik, M. J., & Koper, M. T. M. (2017). Co‐adsorption of Cations as the Cause of the Apparent pH Dependence of Hydrogen Adsorption on a Stepped Platinum Single‐Crystal Electrode. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201709455
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