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Conductive Microporous Covalent Triazine‐Based Framework for High‐Performance Electrochemical Capacitive Energy Storage
Abstract
Nitrogen‐enriched porous nanocarbon, graphene, and conductive polymers attract increasing attention for application in supercapacitors. However, electrode materials with a large specific surface area (SSA) and a high nitrogen doping concentration, which is needed for excellent supercapacitors, has not been achieved thus far. Herein, we developed a class of tetracyanoquinodimethane‐derived conductive microporous covalent triazine‐based frameworks (TCNQ‐CTFs) with both high nitrogen content (>8 %) and large SSA (>3600 m 2 g−1). These CTFs exhibited excellent specific capacitances with the highest value exceeding 380 F g−1, considerable energy density of 42.8 Wh kg−1, and remarkable cycling stability without any capacitance degradation after 10 000 cycles. This class of CTFs should hold a great potential as high‐performance electrode material for electrochemical energy‐storage systems.
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Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Interfacial Polymerization: From Chemistry to Functional Materials
Zhang, F., Fan, J., & Wang, S. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201916473 · Cited by 478
Self-citationNanoscale covalent organic frameworks: from controlled synthesis to cancer therapy
He, X., Jiang, Z., Akakuru, O. U., Li, J., & Wu, A. (2021) · Chemical Communications · doi:10.1039/d1cc04846e · Cited by 303
Conjugated porous polymers: incredibly versatile materials with far-reaching applications
Taylor, D., Dalgarno, S. J., Xu, Z., & Vilela, F. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00315k · Cited by 259
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Li, Y., Zheng, S., Liu, X., Li, P., Sun, L., Yang, R., Wang, S., Wu, Z., Bao, X., & Deng, W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-12-04
- Volume
- 57
- Issue
- 27
- Pages
- 7992-7996
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2768654171
- Cited by
- 249
- References
- 1
- FWCI
- 8.37
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- Natural Science Foundation of Liaoning Province (201602737)
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- Li, Y., Zheng, S., Liu, X., Li, P., Sun, L., Yang, R., Wang, S., Wu, Z., Bao, X., & Deng, W. (2018). Conductive Microporous Covalent Triazine‐Based Framework for High‐Performance Electrochemical Capacitive Energy Storage. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201711169
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