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Interpretation of Raman spectra of disordered and amorphous carbon

Ferrari, A. C., Robertson, J.·2000·Physical Review B
DOI 10.1103/physrevb.61.14095
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Abstract

The model and theoretical understanding of the Raman spectra in disordered and amorphous carbon are given. The nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of \ensuremath{\pi} states and the long-range polarizability of \ensuremath{\pi} bonding. Visible Raman data on disordered, amorphous, and diamondlike carbon are classified in a three-stage model to show the factors that control the position, intensity, and widths of the G and D peaks. It is shown that the visible Raman spectra depend formally on the configuration of the ${\mathrm{sp}}^{2}$ sites in ${\mathrm{sp}}^{2}$-bonded clusters. In cases where the ${\mathrm{sp}}^{2}$ clustering is controlled by the ${\mathrm{sp}}^{3}$ fraction, such as in as-deposited tetrahedral amorphous carbon (ta-C) or hydrogenated amorphous carbon (a-C:H) films, the visible Raman parameters can be used to derive the ${\mathrm{sp}}^{3}$ fraction.

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Metadata

Authors
Ferrari, A. C., & Robertson, J.
Venue
Physical Review B
Publisher
American Physical Society (APS)
Published
2000-05-15
Volume
61
Issue
20
Pages
14095-14107
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
DOI
10.1103/physrevb.61.14095
OpenAlex
W2235679284
Cited by
15,651
References
0
FWCI
82.40
Type
journal article
Language
en
Open access
closed
Licence
link.aps.org/licenses/aps-default-license (vor)

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Ferrari, A. C., & Robertson, J. (2000). Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review B. https://doi.org/10.1103/physrevb.61.14095

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