The DOI matches its Crossref record.
A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF‐8, an Efficient and Robust Electrocatalyst
Abstract
Keggin‐type polyoxometalate anions [XM 12 O 40]n− are versatile, as their applications in interdisciplinary areas show. The Keggin anion [CoW 12 O 40]6− turns into an efficient and robust electrocatalyst upon its confinement in the well‐defined void space of ZIF‐8, a metal–organic framework (MOF). [H 6 CoW 12 O 40]@ZIF‐8 is so stable to water oxidation that it retains its initial activity even after 1000 catalytic cycles. The catalyst has a turnover frequency (TOF) of 10.8 mol O 2(mol Co)−1 s−1, one of the highest TOFs for electrocatalytic oxygen evolution at neutral pH. Controlled experiments rule out the chances of formation and participation of CoOx in this electrocatalyic water oxidation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks
Samaniyan, M., Mirzaei, M., Khajavian, R., Eshtiagh-Hosseini, H., & Streb, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03439 · Cited by 389
Huang, J., Li, Y., Huang, R., He, C., Gong, L., Hu, Q., Wang, L., Xu, Y., Tian, X., Liu, S., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201801029 · Cited by 341
Polyoxometalated metal-organic framework superstructure for stable water oxidation
Yue, K., Lu, R., Gao, M., Song, F., Dai, Y., Xia, C., Mei, B., Dong, H., Qi, R., Zhang, D., et al. (2025) · Science · doi:10.1126/science.ads1466 · Cited by 322
Metadata
- Authors
- Mukhopadhyay, S., Debgupta, J., Singh, C., Kar, A., & Das, S. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-01-16
- Volume
- 57
- Issue
- 7
- Pages
- 1918-1923
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2771345288
- Cited by
- 192
- References
- 0
- FWCI
- 8.02
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF‐8, an Efficient and Robust Electrocatalyst. https://app.cochat.ai/papers/10.1002/anie.201711920
- The paper
- Mukhopadhyay, S., Debgupta, J., Singh, C., Kar, A., & Das, S. K. (2018). A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF‐8, an Efficient and Robust Electrocatalyst. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201711920
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
