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Cited by 305

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Direct Synthesis of a Covalent Triazine‐Based Framework from Aromatic Amides

Yu, Soo‐Young, Mahmood, Javeed, Noh, Hyuk‐Jun, Seo, Jeong‐Min, Jung, Sun‐Min, Shin, Sun‐Hee, Im, Yoon‐Kwang, Jeon, In‐Yup, Baek, Jong‐Beom·2018·Angewandte Chemie International Edition

Abstract

There have been extensive efforts to synthesize crystalline covalent triazine‐based frameworks (CTFs) for practical applications and to realize their potential. The phosphorus pentoxide (P 2 O 5)‐catalyzed direct condensation of aromatic amide instead of aromatic nitrile to form triazine rings. P 2 O 5‐catalyzed condensation was applied on terephthalamide to construct a covalent triazine‐based framework (p CTF‐1). This approach yielded highly crystalline p CTF‐1 with high specific surface area (2034.1 m 2 g−1). At low pressure, the p CTF‐1 showed high CO 2 (21.9 wt % at 273 K) and H 2 (1.75 wt % at 77 K) uptake capacities. The direct formation of a triazine‐based COF was also confirmed by model reactions, with the P 2 O 5‐catalyzed condensation reaction of both benzamide and benzonitrile to form 1,3,5‐triphenyl‐2,4,6‐triazine in high yield.

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Metadata

Authors
Yu, S., Mahmood, J., Noh, H., Seo, J., Jung, S., Shin, S., Im, Y., Jeon, I., & Baek, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-04-23
Volume
57
Issue
28
Pages
8438-8442
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2795716771
Cited by
305
References
3
FWCI
10.48
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Direct Synthesis of a Covalent Triazine‐Based Framework from Aromatic Amides. https://app.cochat.ai/papers/10.1002/anie.201801128
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Yu, S., Mahmood, J., Noh, H., Seo, J., Jung, S., Shin, S., Im, Y., Jeon, I., & Baek, J. (2018). Direct Synthesis of a Covalent Triazine‐Based Framework from Aromatic Amides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201801128

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