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Direct Synthesis of a Covalent Triazine‐Based Framework from Aromatic Amides
Abstract
There have been extensive efforts to synthesize crystalline covalent triazine‐based frameworks (CTFs) for practical applications and to realize their potential. The phosphorus pentoxide (P 2 O 5)‐catalyzed direct condensation of aromatic amide instead of aromatic nitrile to form triazine rings. P 2 O 5‐catalyzed condensation was applied on terephthalamide to construct a covalent triazine‐based framework (p CTF‐1). This approach yielded highly crystalline p CTF‐1 with high specific surface area (2034.1 m 2 g−1). At low pressure, the p CTF‐1 showed high CO 2 (21.9 wt % at 273 K) and H 2 (1.75 wt % at 77 K) uptake capacities. The direct formation of a triazine‐based COF was also confirmed by model reactions, with the P 2 O 5‐catalyzed condensation reaction of both benzamide and benzonitrile to form 1,3,5‐triphenyl‐2,4,6‐triazine in high yield.
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Cites
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Brief Review of the Chemistry of Polyphosphoric Acid (PPA) and Bitumen
Masson, J.-F. (2008) · Energy & Fuels · doi:10.1021/ef800120x · Cited by 165
Construction and Characterization of Structure Models of Crystalline Porous Polymers
Martin, R. L., & Haranczyk, M. (2014) · Crystal Growth & Design · doi:10.1021/cg500158c · Cited by 116
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Ju, Q., Ma, R., Pei, Y., Guo, B., Li, Z., Liu, Q., Thomas, T., Yang, M., Hutchings, G. J., & Wang, J. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000067 · Cited by 65
Metadata
- Authors
- Yu, S., Mahmood, J., Noh, H., Seo, J., Jung, S., Shin, S., Im, Y., Jeon, I., & Baek, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-04-23
- Volume
- 57
- Issue
- 28
- Pages
- 8438-8442
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2795716771
- Cited by
- 305
- References
- 3
- FWCI
- 10.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, S., Mahmood, J., Noh, H., Seo, J., Jung, S., Shin, S., Im, Y., Jeon, I., & Baek, J. (2018). Direct Synthesis of a Covalent Triazine‐Based Framework from Aromatic Amides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201801128
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