The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Oxygen Vacancies in Amorphous InOx Nanoribbons Enhance CO2 Adsorption and Activation for CO2 Electroreduction
Abstract
Tuning surface electron transfer process by oxygen (O)‐vacancy engineering is an efficient strategy to develop enhanced catalysts for CO 2 electroreduction (CO 2 ER). Herein, a series of distinct InOx NRs with different numbers of O‐vacancies, namely, pristine (P‐InOx), low vacancy (O‐InOx) and high‐vacancy (H‐InO x) NRs, have been prepared by simple thermal treatments. The H‐InOx NRs show enhanced performance with a best formic acid (HCOOH) selectivity of up to 91.7 % as well as high HCOOH partial current density over a wide range of potentials, largely outperforming those of the P‐InOx and O‐InOx NRs. The H‐InOx NRs are more durable and have a limited activity decay after continuous operating for more than 20 h. The improved performance is attributable to the abundant O‐vacancies in the amorphous H‐InOx NRs, which optimizes CO 2 adsorption/activation and facilitates electron transfer for efficient CO 2 ER.
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Cites
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374
Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171
Chen, Z., Song, Y., Cai, J., Zheng, X., Han, D., Wu, Y., Zang, Y., Niu, S., Liu, Y., Zhu, J., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201801834 · Cited by 1,075
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Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402
Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Oxygen vacancies in metal oxides: recent progress towards advanced catalyst design
Zhuang, G., Chen, Y., Zhuang, Z., Yu, Y., & Yu, J. (2020) · Science China Materials · doi:10.1007/s40843-020-1305-6 · Cited by 499
Amorphization activated ruthenium-tellurium nanorods for efficient water splitting
Wang, J., Han, L., Huang, B., Shao, Q., Xin, H. L., & Huang, X. (2019) · Nature Communications · doi:10.1038/s41467-019-13519-1 · Cited by 489
Self-citationFeng, Y., Yang, H., Zhang, Y., Huang, X., Li, L., Cheng, T., & Shao, Q. (2020) · Nano Letters · doi:10.1021/acs.nanolett.0c03400 · Cited by 396
Self-citationYe, K., Zhou, Z., Shao, J., Lin, L., Gao, D., Ta, N., Si, R., Wang, G., & Bao, X. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201916538 · Cited by 373
Metadata
- Authors
- Zhang, J., Yin, R., Shao, Q., Zhu, T., & Huang, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-03-20
- Volume
- 58
- Issue
- 17
- Pages
- 5609-5613
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2920093770
- Cited by
- 379
- References
- 6
- FWCI
- 10.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, J., Yin, R., Shao, Q., Zhu, T., & Huang, X. (2019). Oxygen Vacancies in Amorphous InOx Nanoribbons Enhance CO2 Adsorption and Activation for CO2 Electroreduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201900167
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