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Cited by 373

The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.

In Situ Reconstruction of a Hierarchical Sn‐Cu/SnOxCore/Shell Catalyst for High‐Performance CO2Electroreduction

Ye, Ke, Zhou, Zhiwen, Shao, Jiaqi, Lin, Long, Gao, Dunfeng, Ta, Na, Si, Rui, Wang, Guoxiong, Bao, Xinhe·2020·Angewandte Chemie International Edition

Abstract

The electrochemical CO 2 reduction reaction (CO 2 RR) to give C 1(formate and CO) products is one of the most techno‐economically achievable strategies for alleviating CO 2 emissions. Now, it is demonstrated that the SnOxshell in Sn 2.7 Cu catalyst with a hierarchical Sn‐Cu core can be reconstructed in situ under cathodic potentials of CO 2 RR. The resulting Sn 2.7 Cu catalyst achieves a high current density of 406.7±14.4 mA cm−2 with C 1 Faradaic efficiency of 98.0±0.9 % at −0.70 V vs. RHE, and remains stable at 243.1±19.2 mA cm−2 with a C 1 Faradaic efficiency of 99.0±0.5 % for 40 h at −0.55 V vs. RHE. DFT calculations indicate that the reconstructed Sn/SnOxinterface facilitates formic acid production by optimizing binding of the reaction intermediate HCOO* while promotes Faradaic efficiency of C 1 products by suppressing the competitive hydrogen evolution reaction, resulting in high Faradaic efficiency, current density, and stability of CO 2 RR at low overpotentials.

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Metadata

Authors
Ye, K., Zhou, Z., Shao, J., Lin, L., Gao, D., Ta, N., Si, R., Wang, G., & Bao, X.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-02-04
Volume
59
Issue
12
Pages
4814-4821
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2999656933
Cited by
373
References
52
FWCI
12.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: In Situ Reconstruction of a Hierarchical Sn‐Cu/SnOxCore/Shell Catalyst for High‐Performance CO2Electroreduction. https://app.cochat.ai/papers/10.1002/anie.201916538
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Ye, K., Zhou, Z., Shao, J., Lin, L., Gao, D., Ta, N., Si, R., Wang, G., & Bao, X. (2020). In Situ Reconstruction of a Hierarchical Sn‐Cu/SnOxCore/Shell Catalyst for High‐Performance CO2Electroreduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201916538

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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