The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
General π‐Electron‐Assisted Strategy for Ir, Pt, Ru, Pd, Fe, Ni Single‐Atom Electrocatalysts with Bifunctional Active Sites for Highly Efficient Water Splitting
Abstract
Both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) are crucial to water splitting, but require alternative active sites. Now, a general π‐electron‐assisted strategy to anchor single‐atom sites (M=Ir, Pt, Ru, Pd, Fe, Ni) on a heterogeneous support is reported. The M atoms can simultaneously anchor on two distinct domains of the hybrid support, four‐fold N/C atoms (M@NC), and centers of Co octahedra (M@Co), which are expected to serve as bifunctional electrocatalysts towards the HER and the OER. The Ir catalyst exhibits the best water‐splitting performance, showing a low applied potential of 1.603 V to achieve 10 mA cm−2 in 1.0 m KOH solution with cycling over 5 h. DFT calculations indicate that the Ir@Co (Ir) sites can accelerate the OER, while the Ir@NC 3 sites are responsible for the enhanced HER, clarifying the unprecedented performance of this bifunctional catalyst towards full water splitting.
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Cites
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
High performance platinum single atom electrocatalyst for oxygen reduction reaction
Liu, J., Jiao, M., Lu, L., Barkholtz, H. M., Li, Y., Wang, Y., Jiang, L., Wu, Z., Liu, D.-J., Zhuang, L., et al. (2017) · Nature Communications · doi:10.1038/ncomms15938 · Cited by 772
Self-citationZhang, C., Sha, J., Fei, H., Liu, M., Yazdi, S., Zhang, J., Zhong, Q., Zou, X., Zhao, N., Yu, H., et al. (2017) · ACS Nano · doi:10.1021/acsnano.7b02148 · Cited by 545
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Cited by
Hu, Q., Gao, K., Wang, X., Zheng, H., Cao, J., Mi, L., Huo, Q., Yang, H., Liu, J., & He, C. (2022) · Nature Communications · doi:10.1038/s41467-022-31660-2 · Cited by 744
Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis
Yang, Q., Liu, H., Yuan, P., Jia, Y., Zhuang, L., Zhang, H., Yan, X., Liu, G., Zhao, Y., Liu, J., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10814 · Cited by 351
Self-citationUniversal strategies to multi-dimensional noble-metal-based catalysts for electrocatalysis
Gao, F., Zhang, Y., Wu, Z., You, H., & Du, Y. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213825 · Cited by 221
Feng, T., Yu, G., Tao, S., Zhu, S., Ku, R., Zhang, R., Zeng, Q., Yang, M., Chen, Y., Chen, W., et al. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta02496a · Cited by 130
Zhang, L., Jang, H., Wang, Y., Li, Z., Zhang, W., Kim, M. G., Yang, D., Liu, S., Liu, X., & Cho, J. (2021) · Advanced Science · doi:10.1002/advs.202004516 · Cited by 118
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Metadata
- Authors
- Lai, W., Zhang, L., Hua, W., Indris, S., Yan, Z., Hu, Z., Zhang, B., Liu, Y., Wang, L., Liu, M., Liu, R., Wang, Y., Wang, J., Hu, Z., Liu, H., Chou, S., & Dou, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-07-10
- Volume
- 58
- Issue
- 34
- Pages
- 11868-11873
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2949754309
- Cited by
- 330
- References
- 3
- FWCI
- 8.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lai, W., Zhang, L., Hua, W., Indris, S., Yan, Z., Hu, Z., Zhang, B., Liu, Y., Wang, L., Liu, M., Liu, R., Wang, Y., Wang, J., Hu, Z., Liu, H., Chou, S., & Dou, S. (2019). General π‐Electron‐Assisted Strategy for Ir, Pt, Ru, Pd, Fe, Ni Single‐Atom Electrocatalysts with Bifunctional Active Sites for Highly Efficient Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201904614
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