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Cited by 330

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General π‐Electron‐Assisted Strategy for Ir, Pt, Ru, Pd, Fe, Ni Single‐Atom Electrocatalysts with Bifunctional Active Sites for Highly Efficient Water Splitting

Lai, Wei‐Hong, Zhang, Li‐Fu, Hua, Wei‐Bo, Indris, Sylvio, Yan, Zi‐Chao, Hu, Zhe, Zhang, Binwei, Liu, Yani, Wang, Li, Liu, Min, Liu, Rong, Wang, Yun‐Xiao, Wang, Jia‐Zhao, Hu, Zhenpeng, Liu, Hua‐Kun, Chou, Shu‐Lei, Dou, Shi‐Xue·2019·Angewandte Chemie International Edition

Abstract

Both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) are crucial to water splitting, but require alternative active sites. Now, a general π‐electron‐assisted strategy to anchor single‐atom sites (M=Ir, Pt, Ru, Pd, Fe, Ni) on a heterogeneous support is reported. The M atoms can simultaneously anchor on two distinct domains of the hybrid support, four‐fold N/C atoms (M@NC), and centers of Co octahedra (M@Co), which are expected to serve as bifunctional electrocatalysts towards the HER and the OER. The Ir catalyst exhibits the best water‐splitting performance, showing a low applied potential of 1.603 V to achieve 10 mA cm−2 in 1.0 m KOH solution with cycling over 5 h. DFT calculations indicate that the Ir@Co (Ir) sites can accelerate the OER, while the Ir@NC 3 sites are responsible for the enhanced HER, clarifying the unprecedented performance of this bifunctional catalyst towards full water splitting.

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Metadata

Authors
Lai, W., Zhang, L., Hua, W., Indris, S., Yan, Z., Hu, Z., Zhang, B., Liu, Y., Wang, L., Liu, M., Liu, R., Wang, Y., Wang, J., Hu, Z., Liu, H., Chou, S., & Dou, S.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-07-10
Volume
58
Issue
34
Pages
11868-11873
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2949754309
Cited by
330
References
3
FWCI
8.09
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: General π‐Electron‐Assisted Strategy for Ir, Pt, Ru, Pd, Fe, Ni Single‐Atom Electrocatalysts with Bifunctional Active Sites for Highly Efficient Water Splitting. https://app.cochat.ai/papers/10.1002/anie.201904614
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Lai, W., Zhang, L., Hua, W., Indris, S., Yan, Z., Hu, Z., Zhang, B., Liu, Y., Wang, L., Liu, M., Liu, R., Wang, Y., Wang, J., Hu, Z., Liu, H., Chou, S., & Dou, S. (2019). General π‐Electron‐Assisted Strategy for Ir, Pt, Ru, Pd, Fe, Ni Single‐Atom Electrocatalysts with Bifunctional Active Sites for Highly Efficient Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201904614

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