The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction
Abstract
Layered two‐dimensional (2D) conjugated metal–organic frameworks (MOFs) represent a family of rising electrocatalysts for the oxygen reduction reaction (ORR), due to the controllable architectures, excellent electrical conductivity, and highly exposed well‐defined molecular active sites. Herein, we report a copper phthalocyanine based 2D conjugated MOF with square‐planar cobalt bis(dihydroxy) complexes (Co‐O 4) as linkages (PcCu‐O 8‐Co) and layer‐stacked structures prepared via solvothermal synthesis. PcCu‐O 8‐Co 2D MOF mixed with carbon nanotubes exhibits excellent electrocatalytic ORR activity (E1/2=0.83 V vs. RHE, n=3.93, and jL=5.3 mA cm−2) in alkaline media, which is the record value among the reported intrinsic MOF electrocatalysts. Supported by in situ Raman spectro‐electrochemistry and theoretical modeling as well as contrast catalytic tests, we identified the cobalt nodes as ORR active sites. Furthermore, when employed as a cathode electrocatalyst for zinc–air batteries, PcCu‐O 8‐Co delivers a maximum power density of 94 mW cm−2, outperforming the state‐of‐the‐art Pt/C electrocatalysts (78.3 mW cm−2).
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Cites
The Chemistry and Applications of Metal-Organic Frameworks
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Cited by
Zhao, Y., Adiyeri Saseendran, D. P., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00515 · Cited by 802
Zhong, H., Ghorbani-Asl, M., Ly, K. H., Zhang, J., Ge, J., Wang, M., Liao, Z., Makarov, D., Zschech, E., Brunner, E., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-15141-y · Cited by 517
Self-citationChen, G., Liu, P., Liao, Z., Sun, F., He, Y., Zhong, H., Zhang, T., Zschech, E., Chen, M., Wu, G., et al. (2020) · Advanced Materials · doi:10.1002/adma.201907399 · Cited by 432
Self-citationLi, W.-H., Deng, W.-H., Wang, G.-E., & Xu, G. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100029 · Cited by 373
Recent progress in metal–organic frameworks (MOFs) for electrocatalysis
Li, C., Zhang, H., Liu, M., Lang, F.-F., Pang, J., & Bu, X.-H. (2023) · Industrial Chemistry & Materials · doi:10.1039/d2im00063f · Cited by 339
Metadata
- Authors
- Zhong, H., Ly, K. H., Wang, M., Krupskaya, Y., Han, X., Zhang, J., Zhang, J., Kataev, V., Büchner, B., Weidinger, I. M., Kaskel, S., Liu, P., Chen, M., Dong, R., & Feng, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-07
- Volume
- 58
- Issue
- 31
- Pages
- 10677-10682
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2954068093
- Cited by
- 422
- References
- 53
- FWCI
- 10.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhong, H., Ly, K. H., Wang, M., Krupskaya, Y., Han, X., Zhang, J., Zhang, J., Kataev, V., Büchner, B., Weidinger, I. M., Kaskel, S., Liu, P., Chen, M., Dong, R., & Feng, X. (2019). A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201907002
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