The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Aqueous Batteries Operated at −50 °C
Abstract
Insufficient ionic conductivity and freezing of the electrolyte are considered the main problems for electrochemical energy storage at low temperatures (low T). Here, an electrolyte with a freezing point lower than −130 °C is developed by using dimethyl sulfoxide (DMSO) as an additive with molar fraction of 0.3 to an aqueous solution of 2 m NaClO 4 (2M‐0.3 electrolyte). The 2M‐0.3 electrolyte exhibits sufficient ionic conductivity of 0.11 mS cm −1 at −50 °C. The combination of spectroscopic investigations and molecular dynamics (MD) simulations reveal that hydrogen bonds are stably formed between DMSO and water molecules, facilitating the operation of the electrolyte at ultra‐low T. Using DMSO as the electrolyte additive, the aqueous rechargeable alkali‐ion batteries (AABs) can work well even at −50 °C. This work provides a simple and effective strategy to develop low T AABs.
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“Tao's group [81] designed an ultralow freezing point electrolyte using DMSO as additive with 0.3 molar fraction, enabling a capacity retention as high as 60% of its RT capacity at -50 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [81]
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Smart, M. C., Ratnakumar, B. V., Chin, K. B., & Whitcanack, L. D. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3501236 · Cited by 220
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Solvation Structure Design for Aqueous Zn Metal Batteries.
Cao, L.-S., Li, D., Hu, E., Xu, J.-J., Deng, T., Ma, L., Wang, Y., Yang, X.-Q., & Wang, C.-S. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c09794 · Cited by 1,077
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Metadata
- Authors
- Nian, Q., Wang, J., Liu, S., Sun, T., Zheng, S., Zhang, Y., Tao, Z., & Chen, J.
- Affiliations
- Nankai University (CN)
- Dalian Institute of Chemical Physics (CN)
- Shandong University (CN)
- Corresponding author
- Tao, Zhanliang
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-10-15
- Volume
- 58
- Issue
- 47
- Pages
- 16994-16999
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2974348764
- Cited by
- 426
- References
- 0
- Citations by year
- 2026: 32 · 2025: 59 · 2024: 99 · 2023: 70 · 2022: 74 · 2021: 59 · 2020: 32 · 2019: 1
- FWCI
- 2.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (51771094,21835004)
- Ministry of Education (B12015 and IRT13R30)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Aqueous and Flow Batteries
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- aqueous batteries, low-temperature batteries, NaClO4 electrolyte, ionic conductivity, hydrogen bonding, alkali-ion batteries, molecular dynamics simulation, electrochemical energy storage
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