A new approach toward improved low temperature performance of Li-ion battery
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Zhang et al. found that although a LiBF4-based electrolyte has an overall lower ionic conductivity than the electrolyte using LiPF6, it delivered higher capacity at -30 °C than the LiPF6-based electrolyte.
“Zhang et al. [95] found that although a LiBF 4 -based electrolyte has an overall lower ionic conductivity than the electrolyte using LiPF 6 , it delivered higher capacity at -30 °C than the LiPF 6 -based electrolyte, as shown in Fig. 12a.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
The interphase impedance, especially the charge transfer resistance of the LiBF4-based electrolyte, is lower than that of the LiPF6-based electrolyte, showing the origin of the capacity difference.
“It can be clearly seen that the interphase impedance, especially the charge transfer resistance of the LiBF 4 -based electrolyte, is lower than that of the LiPF 6 -based electrolyte, showing the origin of the capacity difference.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
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Microporous gel electrolyte Li-ion battery
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- Authors
- Zhang, S. S., Xu, K., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Zhang, S.S
- Venue
- Electrochemistry Communications
- Publisher
- Elsevier BV
- Published
- 2002-11
- Volume
- 4
- Issue
- 11
- Pages
- 928-932
- ISSN
- 1388-2481 (ISSN-L)
- OpenAlex
- W2048302690
- Cited by
- 302
- References
- 0
- Citations by year
- 2026: 9 · 2025: 28 · 2024: 19 · 2023: 30 · 2022: 37 · 2021: 19 · 2020: 25 · 2019: 25 · 2018: 10 · 2017: 19 · 2016: 12 · 2015: 12 · 2014: 7 · 2013: 7 · 2012: 6
- FWCI
- 3.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochemistry Communications (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, low-temperature performance, electrolyte formulation, lithium tetrafluoroborate, LiPF6, ionic conductivity, propylene carbonate, ethylene carbonate, capacity retention, polarization, charge transfer resistance, cell impedance
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