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Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS2 Arrays for High‐Efficiency Hydrogen Evolution Reaction

Open access
Deng, Shengjue, Luo, Mi, Ai, Changzhi, Zhang, Yan, Liu, Bo, Huang, Lei, Jiang, Zheng, Zhang, Qinghua, Gu, Lin, Lin, Shiwei, Wang, Xiuli, Yu, Lei, Wen, Jianguo, Wang, Jiaao, Pan, Guoxiang, Xia, Xinhui, Tu, Jiangping·2019·Angewandte Chemie International Edition

Abstract

A synergistic N doping plus PO 43− intercalation strategy is used to induce high conversion (ca. 41 %) of 2H‐MoS 2 into 1T‐MoS 2, which is much higher than single N doping (ca. 28 %) or single PO 43− intercalation (ca. 10 %). A scattering mechanism is proposed to illustrate the synergistic phase transformation from the 2H to the 1T phase, which was confirmed by synchrotron radiation and spherical aberration TEM. To further enhance reaction kinetics, the designed (N,PO 43−)‐MoS 2 nanosheets are combined with conductive vertical graphene (VG) skeleton forming binder‐free arrays for high‐efficiency hydrogen evolution reaction (HER). Owing to the decreased band gap, lower d‐band center, and smaller hydrogen adsorption/desorption energy, the designed (N,PO 43−)‐MoS 2/VG electrode shows excellent HER performance with a lower Tafel slope and overpotential than N‐MoS 2/VG, PO 43−‐MoS 2/VG counterparts, and other Mo‐base catalysts in the literature.

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Metadata

Authors
Deng, S., Luo, M., Ai, C., Zhang, Y., Liu, B., Huang, L., Jiang, Z., Zhang, Q., Gu, L., Lin, S., Wang, X., Yu, L., Wen, J., Wang, J., Pan, G., Xia, X., & Tu, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-09-24
Volume
58
Issue
45
Pages
16289-16296
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2975540334
Cited by
260
References
5
FWCI
7.42
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS2 Arrays for High‐Efficiency Hydrogen Evolution Reaction. https://app.cochat.ai/papers/10.1002/anie.201909698
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Deng, S., Luo, M., Ai, C., Zhang, Y., Liu, B., Huang, L., Jiang, Z., Zhang, Q., Gu, L., Lin, S., Wang, X., Yu, L., Wen, J., Wang, J., Pan, G., Xia, X., & Tu, J. (2019). Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS2 Arrays for High‐Efficiency Hydrogen Evolution Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201909698

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