The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Controlled Synthesis of a Vacancy‐Defect Single‐Atom Catalyst for Boosting CO2 Electroreduction
Abstract
The reaction of precursors containing both nitrogen and oxygen atoms with Ni II under 500 °C can generate a N/O mixing coordinated Ni‐N 3 O single‐atom catalyst (SAC) in which the oxygen atom can be gradually removed under high temperature due to the weaker Ni−O interaction, resulting in a vacancy‐defect Ni‐N 3‐V SAC at Ni site under 800 °C. For the reaction of Ni II with the precursor simply containing nitrogen atoms, only a no‐vacancy‐defect Ni‐N 4 SAC was obtained. Experimental and DFT calculations reveal that the presence of a vacancy‐defect in Ni‐N 3‐V SAC can dramatically boost the electrocatalytic activity for CO 2 reduction, with extremely high CO 2 reduction current density of 65 mA cm−2 and high Faradaic efficiency over 90 % at −0.9 V vs. RHE, as well as a record high turnover frequency of 1.35×10 5 h−1, much higher than those of Ni‐N 4 SAC, and being one of the best reported electrocatalysts for CO 2‐to‐CO conversion to date.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
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Self-citationFei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
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Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
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Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
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Self-citationJiang, K., Siahrostami, S., Akey, A. J., Li, Y., Lu, Z., Lattimer, J., Hu, Y., Stokes, C., Gangishetty, M., Chen, G., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.09.014 · Cited by 406
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Jiao, L., Yang, W., Wan, G., Zhang, R., Zheng, X., Zhou, H., Yu, S., & Jiang, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202008787 · Cited by 412
Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis
Yang, Q., Liu, H., Yuan, P., Jia, Y., Zhuang, L., Zhang, H., Yan, X., Liu, G., Zhao, Y., Liu, J., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10814 · Cited by 351
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Metadata
- Authors
- Rong, X., Wang, H., Lu, X., Si, R., & Lu, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-12-16
- Volume
- 59
- Issue
- 5
- Pages
- 1961-1965
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2985567728
- Cited by
- 378
- References
- 8
- FWCI
- 9.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rong, X., Wang, H., Lu, X., Si, R., & Lu, T. (2020). Controlled Synthesis of a Vacancy‐Defect Single‐Atom Catalyst for Boosting CO2 Electroreduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201912458
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