The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte
Abstract
Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester‐based electrolyte is successfully demonstrated, which enables high‐voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO 3 additive presents an excellent Coulombic efficiency up to 98.8 % during stable galvanostatic lithium plating/stripping cycles. A full‐cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high‐voltage lithium metal batteries.
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Cites
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
High rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Capacity Fade Mechanisms and Side Reactions in Lithium‐Ion Batteries
Arora, P., White, R. E., & Doyle, M. (1998) · Journal of The Electrochemical Society · doi:10.1149/1.1838857 · Cited by 1,408
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes
Chen, S., Zheng, J., Yu, L., Ren, X., Engelhard, M. H., Niu, C., Lee, H., Xu, W., Xiao, J., Liu, J., et al. (2018) · Joule · doi:10.1016/j.joule.2018.05.002 · Cited by 654
Cited by
A Review of Solid Electrolyte Interphase (SEI) and Dendrite Formation in Lithium Batteries
Li, B., Chao, Y., Li, M., Xiao, Y., Li, R., Yang, K., Cui, X., Xu, G., Li, L., Yang, C., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00147-5 · Cited by 406
Wu, Y., Hu, Q., Liang, H., Wang, A., Xu, H., Wang, L., & He, X. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300259 · Cited by 270
Insights into the deposition chemistry of Li ions in nonaqueous electrolyte for stable Li anodes
Wang, Z., Sun, Z., Li, J., Shi, Y., Sun, C., An, B., Cheng, H.-M., & Li, F. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01017k · Cited by 268
Han, Y., Liu, B., Xiao, Z., Zhang, W., Wang, X., Pan, G., Xia, Y., Xia, X., & Tu, J. (2021) · InfoMat · doi:10.1002/inf2.12166 · Cited by 267
Wang, Z., Sun, Z., Shi, Y., Qi, F., Gao, X., Yang, H., Cheng, H., & Li, F. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100935 · Cited by 202
Metadata
- Authors
- Jie, Y., Liu, X., Lei, Z., Wang, S., Chen, Y., Huang, F., Cao, R., Zhang, G., & Jiao, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-01-21
- Volume
- 59
- Issue
- 9
- Pages
- 3505-3510
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2997649224
- Cited by
- 246
- References
- 5
- FWCI
- 8.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jie, Y., Liu, X., Lei, Z., Wang, S., Chen, Y., Huang, F., Cao, R., Zhang, G., & Jiao, S. (2020). Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201914250
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