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Cited by 1,408Advanced Battery Technologies ResearchAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies

Capacity Fade Mechanisms and Side Reactions in Lithium‐Ion Batteries

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Arora, Pankaj, White, Ralph E., Doyle, Marc·1998·Journal of The Electrochemical Society
DOI 10.1149/1.1838857
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Abstract

The capacity of a lithium‐ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms which are due to or are associated with unwanted side reactions that occur in these batteries. These reactions occur during overcharge or overdischarge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. These capacity loss mechanisms are not included in the present lithium‐ion battery mathematical models available in the open literature. Consequently, these models cannot be used to predict cell performance during cycling and under abuse conditions. This article presents a review of the current literature on capacity fade mechanisms and attempts to describe the information needed and the directions that may be taken to include these mechanisms in advanced lithium‐ion battery models.

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  • During over-discharging, anode potential increases abnormally leading to anodic dissolution of copper current collector and formation of Cu2+ ions; upon recharging, reverse reaction can form copper dendrites, which may lead to internal short circuit.

    “During over-discharging, the anode potential increases abnormally which leads to the anodic dissolution of the copper (Cu) current collector and formation of Cu 2+ ions [37].Upon recharging, the reverse reaction can form copper dendrites, which may lead to internal short circuit [38].”

    From Data-driven health estimation and lifetime prediction of lithium-ion batteries: A review (2019) · cites this paper as [38]

    Split into 2 atoms — 1 confirmed, 1 partially supported, 0 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.

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Authors
Arora, P., White, R. E., & Doyle, M.
Affiliations
DuPont (United States) (US)
ORCID
White, Ralph E.
Venue
Journal of The Electrochemical Society
Publisher
The Electrochemical Society
Published
1998-10-01
Volume
145
Issue
10
Pages
3647-3667
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
DOI
10.1149/1.1838857
OpenAlex
W2014862314
Cited by
1,408
References
0
Citations by year
2026: 43 · 2025: 69 · 2024: 59 · 2023: 75 · 2022: 74 · 2021: 70 · 2020: 89 · 2019: 96 · 2018: 86 · 2017: 117 · 2016: 87 · 2015: 96 · 2014: 92 · 2013: 63 · 2012: 39
FWCI
47.70
Type
journal article
Language
en
Open access
Licence
Locations
  • Journal of The Electrochemical Society (publishedVersion)
  • Scholar Commons (University of South Carolina) (submittedVersion)
Topics
  • Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Keywords
lithium-ion batteries, capacity fade, capacity loss mechanisms, side reactions, overcharging, overdischarge, electrolyte decomposition, passive film formation, active material dissolution, cycling performance

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