The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Fluorinated Aromatic Diluent for High‐Performance Lithium Metal Batteries
Abstract
In lithium metal batteries, electrolytes containing a high concentration of salts have demonstrated promising cyclability, but their practicality with respect to the cost of materials is yet to be proved. Here we report a fluorinated aromatic compound, namely 1,2‐difluorobenzene, for use as a diluent solvent in the electrolyte to realize the “high‐concentration effect”. The low energy level of the lowest unoccupied molecular orbital (LUMO), weak binding affinity for lithium ions, and high fluorine‐donating power of 1,2‐difluorobenzene jointly give rise to the high‐concentration effect at a bulk salt concentration near 2 m, while modifying the composition of the solid‐electrolyte‐interphase (SEI) layer to be rich in lithium fluoride (LiF). The employment of triple salts to prevent corrosion of the aluminum current collector further improves cycling performance. This study offers a design principle for achieving a local high‐concentration effect with reasonably low bulk concentrations of salts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
Li, Y., Li, Y., Pei, A., Yan, K., Sun, Y., Wu, C.-L., Joubert, L.-M., Chin, R., Koh, A. L., Yu, Y., et al. (2017) · Science · doi:10.1126/science.aam6014 · Cited by 1,547
Wang, X., Zhang, M., Alvarado, J., Wang, S., Sina, M., Lu, B., Bouwer, J., Xu, W., Xiao, J., Zhang, J.-G., et al. (2017) · Nano Letters · doi:10.1021/acs.nanolett.7b03606 · Cited by 409
Localized high concentration electrolyte behavior near a lithium–metal anode surface
Zheng, Y., Soto, F. A., Ponce, V., Seminario, J. M., Cao, X., Zhang, J.-G., & Balbuena, P. B. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta08935g · Cited by 123
Cited by
High-voltage liquid electrolytes for Li batteries: progress and perspectives
Fan, X., & Wang, C. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00450f · Cited by 980
Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries
Liu, Y., Tao, X., Wang, Y., Jiang, C., Ma, C., Sheng, O., Lu, G., & Lou, X. W. (. (2022) · Science · doi:10.1126/science.abn1818 · Cited by 962
Rajendran, S., Priya, T. A. K., Khoo, K. S., Hoang, T. K. A., Ng, H.-S., Munawaroh, H. S. H., Karaman, C., Orooji, Y., & Show, P. L. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2021.132369 · Cited by 570
Zhao, Y., Zhou, T., Ashirov, T., Kazzi, M. E., Cancellieri, C., Jeurgens, L. P. H., Choi, J. W., & Coskun, A. (2022) · Nature Communications · doi:10.1038/s41467-022-29199-3 · Cited by 465
Self-citationA review on the failure and regulation of solid electrolyte interphase in lithium batteries
Ding, J.-F., Xu, R., Yan, C., Li, B.-Q., Yuan, H., & Huang, J.-Q. (2021) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.11.016 · Cited by 313
Metadata
- Authors
- Yoo, D., Yang, S., Kim, K. J., & Choi, J. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-06-17
- Volume
- 59
- Issue
- 35
- Pages
- 14869-14876
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3027532879
- Cited by
- 243
- References
- 3
- FWCI
- 10.21
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Fluorinated Aromatic Diluent for High‐Performance Lithium Metal Batteries. https://app.cochat.ai/papers/10.1002/anie.202003663
- The paper
- Yoo, D., Yang, S., Kim, K. J., & Choi, J. W. (2020). Fluorinated Aromatic Diluent for High‐Performance Lithium Metal Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202003663
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
