The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries
Open accessAbstract
The development of new solvents is imperative in lithium metal batteries due to the incompatibility of conventional carbonate and narrow electrochemical windows of ether-based electrolytes. Whereas the fluorinated ethers showed improved electrochemical stabilities, they can hardly solvate lithium ions. Thus, the challenge in electrolyte chemistry is to combine the high voltage stability of fluorinated ethers with high lithium ion solvation ability of ethers in a single molecule. Herein, we report a new solvent, 2,2-dimethoxy-4-(trifluoromethyl)-1,3-dioxolane (DTDL), combining a cyclic fluorinated ether with a linear ether segment to simultaneously achieve high voltage stability and tune lithium ion solvation ability and structure. High oxidation stability up to 5.5 V, large lithium ion transference number of 0.75 and stable Coulombic efficiency of 99.2% after 500 cycles proved the potential of DTDL in high-voltage lithium metal batteries. Furthermore, 20 μm thick lithium paired LiNi 0.8 Co 0.1 Mn 0.1 O 2 full cell incorporating 2 M LiFSI-DTDL electrolyte retained 84% of the original capacity after 200 cycles at 0.5 C.
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Cites
Ultrastructural Characterization of the Lower Motor System in a Mouse Model of Krabbe Disease
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Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Promise and reality of post-lithium-ion batteries with high energy densities
Choi, J. W., & Aurbach, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.13 · Cited by 5,110
Self-citationPathways for practical high-energy long-cycling lithium metal batteries
Liu, J., Bao, Z., Cui, Y., Dufek, E. J., Goodenough, J. B., Khalifah, P., Li, Q., Liaw, B. Y., Liu, P., Manthiram, A., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0338-x · Cited by 3,412
High rate and stable cycling of lithium metal anode
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Advances and issues in developing salt-concentrated battery electrolytes
Yamada, Y., Wang, J., Ko, S., Watanabe, E., & Yamada, A. (2019) · Nature Energy · doi:10.1038/s41560-019-0336-z · Cited by 1,788
Lee, Y.-G., Fujiki, S., Jung, C., Suzuki, N., Yashiro, N., Omoda, R., Ko, D.-S., Shiratsuchi, T., Sugimoto, T., Ryu, S., et al. (2020) · Nature Energy · doi:10.1038/s41560-020-0575-z · Cited by 1,708
Quantifying inactive lithium in lithium metal batteries
Fang, C., Li, J., Zhang, M., Zhang, Y., Yang, F., Lee, J. Z., Lee, M.-H., Alvarado, J., Schroeder, M. A., Yang, Y., et al. (2019) · Nature · doi:10.1038/s41586-019-1481-z · Cited by 1,413
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
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High‐Voltage Lithium‐Metal Batteries Enabled by Localized High‐Concentration Electrolytes
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Cited by
Li, Z., Yu, R., Weng, S., Zhang, Q., Wang, X., & Guo, X. (2023) · Nature Communications · doi:10.1038/s41467-023-35857-x · Cited by 341
Fluorination in advanced battery design
Wang, Y., Wu, Z., Azad, F. M., Zhu, Y., Wang, L., Hawker, C. J., Whittaker, A. K., Forsyth, M., & Zhang, C. (2023) · Nature Reviews Materials · doi:10.1038/s41578-023-00623-4 · Cited by 333
Zhao, Y., Zhou, T., Mensi, M., Choi, J. W., & Coskun, A. (2023) · Nature Communications · doi:10.1038/s41467-023-35934-1 · Cited by 279
Self-citationWu, Y., Hu, Q., Liang, H., Wang, A., Xu, H., Wang, L., & He, X. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300259 · Cited by 270
Metadata
- Authors
- Zhao, Y., Zhou, T., Ashirov, T., Kazzi, M. E., Cancellieri, C., Jeurgens, L. P. H., Choi, J. W., & Coskun, A.
- Venue
- Nature Communications
- Published
- 2022-05-06
- Volume
- 13
- Issue
- 1
- Pages
- 2575-2575
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4229079925
- Cited by
- 465
- References
- 33
- FWCI
- 26.83
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhao, Y., Zhou, T., Ashirov, T., Kazzi, M. E., Cancellieri, C., Jeurgens, L. P. H., Choi, J. W., & Coskun, A. (2022). Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries. Nature Communications. https://doi.org/10.1038/s41467-022-29199-3
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