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Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries

Li, Siyuan, Zhang, Weidong, Wu, Qiang, Fan, Lei, Wang, Xinyang, Wang, Xiao, Shen, Zeyu, He, Yi, Lu, Yingying·2020·Angewandte Chemie International Edition

Abstract

A rechargeable Li metal anode coupled with a high‐voltage cathode is a promising approach to high‐energy‐density batteries exceeding 300 Wh kg−1. Reported here is an advanced dual‐additive electrolyte containing a unique solvation structure and it comprises a tris(pentafluorophenyl)borane additive and LiNO 3 in a carbonate‐based electrolyte. This system generates a robust outer Li 2 O solid electrolyte interface and F‐ and B‐containing conformal cathode electrolyte interphase. The resulting stable ion transport kinetics enables excellent cycling of Li/LiNi 0.8 Mn 0.1 Co 0.1 O 2 for 140 cycles with 80 % capacity retention under highly challenging conditions (≈295.1 Wh kg−1 at cell‐level). The electrolyte also exhibits high cycling stability for a 4.6 V LiCoO 2 (160 cycles with 89.8 % capacity retention) cathode and 4.95 V LiNi 0.5 Mn 1.5 O 4 cathode.

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Metadata

Authors
Li, S., Zhang, W., Wu, Q., Fan, L., Wang, X., Wang, X., Shen, Z., He, Y., & Lu, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-06-09
Volume
59
Issue
35
Pages
14935-14941
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3025473585
Cited by
318
References
4
FWCI
16.79
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries. https://app.cochat.ai/papers/10.1002/anie.202004853
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Li, S., Zhang, W., Wu, Q., Fan, L., Wang, X., Wang, X., Shen, Z., He, Y., & Lu, Y. (2020). Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202004853

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