High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes
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Usage of stronger Li+-coordinating nitriles such as acetonitrile and linear and cyclic ether cosolvents improved salt dissociation and solubility, resulting in a substantial increase at low temperature.
“Usage of the stronger (compared to semifluorinated short alkanes) Li + coordinating nitriles such as acetonitrile, linear and cyclic ether cosolvents improved salt dissociation and solubility resulting in a substantial increase at LT.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [75]
The retrieved copy provides a table of contents, including “Physical-Chemical Properties of Liquefied Gas Electrolytes” and “Low-Temperature Performance,” but no substantive passage from either section. Searches for acetonitrile, cosolvents, semifluorinated alkanes, and salt dissociation or solubility yielded no passage that addresses the claimed low-temperature increase. (LLM, conf=0.72)
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Recent advances on anion-derived sei for fast-charging and stable lithium batteries
Xiao, Y., Xu, R., Xu, L., Ding, J., & Huang, J.-Q. (2021) · Energy Materials · doi:10.20517/energymater.2021.17 · Cited by 59 · see citing works
Realizing high-energy and long-life Li/SPAN batteries
Phan, A. L., Le, P. M., & Wang, C. (2024) · Joule · doi:10.1016/j.joule.2024.04.003 · Cited by 57 · see citing works
Lithium‐Metal Batteries via Suppressing Li Dendrite Growth and Improving Coulombic Efficiency
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Leveraging cryogenic electron microscopy for advancing battery design
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“Yang et al.(30) applied cryo-FIB/SEM to reconstruct the structure of Li metal deposited in different electrolytes, where the porosity and tortuosity of Li metal deposits were found to be positively related to the electrochemical performance of the specific liquid electrolyte (Figure 2E).”
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Self-citationRecent progress in electrolyte design for advanced lithium metal batteries
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“With ACN and THF additives that can dissociate LiTFSI well, liquefied gas electrolytes show greater salt solubility (1.2 mol/L LiTFSI in ACN ‐ FM) and excellent ionic conductivity of 5.8 mS/cm at − 60°C and 4.8 mS/cm at − 78°C. 92,141 Therefore, LMBs with 1.2 mol/L LiTFSI –”
InfluentialAn Ultrafast and Stable Li‐Metal Battery Cycled at −40 °C
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A fast-ion conducting interface enabled by aluminum silicate fibers for stable Li metal batteries
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Spinel-related Li2Ni0.5Mn1.5O4 cathode for 5-V anode-free lithium metal batteries
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Self-citationEdge-Propagation Discharge Mechanism in CFx Batteries—A First-Principles and Experimental Study
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Self-citationCalendar Life of Lithium Metal Batteries: Accelerated Aging and Failure Analysis
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High-Voltage Cyclic Ether-Based Electrolytes for Low-Temperature Sodium-Ion Batteries.
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- Authors
- Yang, Y., Davies, D. M., Yin, Y., Borodin, O., Lee, J. Z., Fang, C., Olguin, M., Zhang, Y., Sablina, E. S., Wang, X., Rustomji, C. S., & Meng, Y. S.
- Affiliations
- University of California San Diego (US)
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Borodin, Oleg
- Rustomji, Cyrus S.
- Meng, Y. Shirley
- ORCID
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2019-08
- Volume
- 3
- Issue
- 8
- Pages
- 1986-2000
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W2955217160
- Cited by
- 268
- References
- 40
- Citations by year
- 2026: 14 · 2025: 40 · 2024: 37 · 2023: 36 · 2022: 49 · 2021: 45 · 2020: 42 · 2019: 5
- FWCI
- 12.68
- Type
- journal article
- Language
- en
- Update notices
- erratum (2019-08-21)
- Open access
- bronze
- doi.org
- Licence
- Locations
- Joule (publishedVersion)
- eScholarship (California Digital Library) (submittedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- U.S. Department of Energy
- National Science Foundation
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced battery technologies research
- Keywords
- lithium metal anode, methyl fluoride, electrolyte solvation structure, lithium transference number, salt dissociation, dendrite suppression, Coulombic efficiency, lithium transport, rate capability, low-temperature cycling, solid-state batteries
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