The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Interfacial Structure of Water as a New Descriptor of the Hydrogen Evolution Reaction
Abstract
Driven by the persisting poor understanding of the sluggish kinetics of the hydrogen evolution reaction (HER) on Pt in alkaline media, a direct correlation of the interfacial water structure and activity is still yet to be established. Herein, using Pt and Pt–Ni nanoparticles we first demonstrate a strong dependence of the proton donor structure on the HER activity and pH. The structure of the first layer changes from the proton acceptors to the donors with increasing pH. In the base, the reactivity of the interfacial water varied its structure, and the activation energies of water dissociation increased in the sequence: the dangling O−H bonds < the trihedrally coordinated water < the tetrahedrally coordinated water. Moreover, optimizing the adsorption of H and OH intermediates can re‐orientate the interfacial water molecules with their H atoms pointing towards the electrode surface, thereby enhancing the kinetics of HER. Our results clarified the dynamic role of the water structure at the electrode–electrolyte interface during HER and the design of highly efficient HER catalysts.
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Cites
Shinagawa, T., Garcia-Esparza, A. T., & Takanabe, K. (2015) · Scientific Reports · doi:10.1038/srep13801 · Cited by 3,287
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Danilovic, N., van der Vliet, D., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2013) · Nature Chemistry · doi:10.1038/nchem.1574 · Cited by 1,426
Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y. (2015) · Nature Communications · doi:10.1038/ncomms6848 · Cited by 1,136
Danilovic, N., Subbaraman, R., Strmcnik, D., Chang, K., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2012) · Angewandte Chemie · doi:10.1002/ange.201204842 · Cited by 262
Zheng, J., Yan, Y., & Xu, B. (2015) · Journal of The Electrochemical Society · doi:10.1149/2.0501514jes · Cited by 176
Cited by
Shi, Y., Ma, Z.-R., Xiao, Y.-Y., Yin, Y.-C., Huang, W.-M., Huang, Z.-C., Zheng, Y.-Z., Mu, F.-Y., Huang, R., Shi, G.-Y., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-23306-6 · Cited by 894
Li, P., Jiang, Y., Hu, Y., Men, Y., Liu, Y., Cai, W., & Chen, S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00846-8 · Cited by 852
Self-citationWater-hydroxide trapping in cobalt tungstate for proton exchange membrane water electrolysis
Ram, R., Xia, L., Benzidi, H., Guha, A., Golovanova, V., Garzón Manjón, A., Llorens Rauret, D., Sanz Berman, P., Dimitropoulos, M., Mundet, B., et al. (2024) · Science · doi:10.1126/science.adk9849 · Cited by 489
Interfacial water engineering boosts neutral water reduction
Sun, K., Wu, X., Zhuang, Z., Liu, L., Fang, J., Zeng, L., Ma, J., Liu, S., Li, J., Dai, R., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-33984-5 · Cited by 363
Lao, M., Li, P., Jiang, Y., Pan, H., Dou, S. X., & Sun, W. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107231 · Cited by 290
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Metadata
- Authors
- Shen, L., Lu, B., Li, Y., Liu, J., Huang‐fu, Z., Peng, H., Ye, J., Qu, X., Zhang, J., Li, G., Cai, W., Jiang, Y., & Sun, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-10-07
- Volume
- 59
- Issue
- 50
- Pages
- 22397-22402
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3083679454
- Cited by
- 479
- References
- 6
- FWCI
- 5.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shen, L., Lu, B., Li, Y., Liu, J., Huang‐fu, Z., Peng, H., Ye, J., Qu, X., Zhang, J., Li, G., Cai, W., Jiang, Y., & Sun, S. (2020). Interfacial Structure of Water as a New Descriptor of the Hydrogen Evolution Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202007567
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