The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
Rational Fabrication of Low‐Coordinate Single‐Atom Ni Electrocatalysts by MOFs for Highly Selective CO2 Reduction
Abstract
Single‐atom catalysts (SACs) have attracted tremendous interests due to their ultrahigh activity and selectivity. However, the rational control over coordination microenvironment of SACs remains a grand challenge. Herein, a post‐synthetic metal substitution (PSMS) strategy has been developed to fabricate single‐atom Ni catalysts with different N coordination numbers (denoted Ni‐Nx‐C) on pre‐designed N‐doped carbon derived from metal‐organic frameworks. When served for CO 2 electroreduction, the obtained Ni‐N 3‐C catalyst achieves CO Faradaic efficiency (FE) up to 95.6 %, much superior to that of Ni‐N 4‐C. Theoretical calculations reveal that the lower Ni coordination number in Ni‐N 3‐C can significantly enhance COOH* formation, thereby accelerating CO 2 reduction. In addition, Ni‐N 3‐C shows excellent performance in Zn–CO 2 battery with ultrahigh CO FE and excellent stability. This work opens up a new and general avenue to coordination microenvironment modulation (MEM) of SACs for CO 2 utilization.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Introduction to Metal–Organic Frameworks
Zhou, H.-C., Long, J. R., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr300014x · Cited by 7,720
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O’Keeffe, M., & Yaghi, O. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602439103 · Cited by 7,563
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Heterogeneous single-atom catalysis
Wang, A., Li, J., & Zhang, T. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0010-1 · Cited by 4,191
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Huang, X., Lin, Y., Zhang, J., & Chen, X. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503778 · Cited by 1,816
Chemical Synthesis of Single Atomic Site Catalysts
Ji, S., Chen, Y., Wang, X., Zhang, Z., Wang, D., & Li, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00818 · Cited by 1,444
Zhu, C., Fu, S., Shi, Q., Du, D., & Lin, Y. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703864 · Cited by 1,345
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
Wang, X., Chen, Z., Zhao, X., Yao, T., Chen, W., You, R., Zhao, C., Wu, G., Wang, J., Huang, W., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712451 · Cited by 1,120
Cited by
Design concept for electrocatalysts
Wang, Y., Zheng, X., & Wang, D. (2022) · Nano Research · doi:10.1007/s12274-021-3794-0 · Cited by 549
Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)
Song, W., Xiao, C., Ding, J., Huang, Z., Yang, X., Zhang, T., Mitlin, D., & Hu, W. (2024) · Advanced Materials · doi:10.1002/adma.202301477 · Cited by 373
Microenvironment Engineering of Single/Dual‐Atom Catalysts for Electrocatalytic Application
Gao, Y., Liu, B., & Wang, D. (2023) · Advanced Materials · doi:10.1002/adma.202209654 · Cited by 319
Meng, D., Zhang, M., Si, D., Mao, M., Hou, Y., Huang, Y., & Cao, R. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202111136 · Cited by 312
Single‐atom catalysis for carbon neutrality
Wang, L., Wang, D., & Li, Y. (2022) · Carbon Energy · doi:10.1002/cey2.194 · Cited by 293
Metadata
- Authors
- Zhang, Y., Jiao, L., Yang, W., Xie, C., & Jiang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-02-26
- Volume
- 60
- Issue
- 14
- Pages
- 7607-7611
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3120007641
- Cited by
- 649
- References
- 53
- FWCI
- 22.03
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Rational Fabrication of Low‐Coordinate Single‐Atom Ni Electrocatalysts by MOFs for Highly Selective CO2 Reduction. https://app.cochat.ai/papers/10.1002/anie.202016219
- The paper
- Zhang, Y., Jiao, L., Yang, W., Xie, C., & Jiang, H. (2021). Rational Fabrication of Low‐Coordinate Single‐Atom Ni Electrocatalysts by MOFs for Highly Selective CO2 Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202016219
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
