The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Facile Synthesis of Two‐Dimensional Iron/Cobalt Metal–Organic Framework for Efficient Oxygen Evolution Electrocatalysis
Abstract
A facile synthesis is reported of two‐dimensional (2D) bimetallic (Fe/Co=1:2) metal–organic frameworks (MOF, ca. 2.2 nm thick) via simple stirring of the reaction mixture of Fe/Co salts and 1,4‐benzene dicarboxylic acid (1,4‐BDC) in the presence of triethylamine and water at room temperature. The mechanism of the 2D, rather than bulk, MOF was revealed by studying the role of each component in the reaction mixture. It was found that these 2D MOF‐Fe/Co(1:2) exhibited excellent electrocatalytic activity for the oxygen evolution reaction (OER) under basic conditions. The electrocatalytic mechanism was disclosed via both experimental results and density functional theory (DFT) calculation. The 2D morphology and co‐doping of Fe/Co contributed to the superior OER performance of the 2D MOF‐Fe/Co(1:2). The simple and efficient synthetic method is suitable for the mass production and future commercialization of functional 2D MOF with low cost and high yield.
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Citations
Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
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Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis
Song, F., & Hu, X. (2014) · Nature Communications · doi:10.1038/ncomms5477 · Cited by 2,332
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
Gorlin, Y., & Jaramillo, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104587v · Cited by 1,566
Two-dimensional metal–organic framework nanosheets: synthesis and applications
Zhao, M., Huang, Y., Peng, Y., Huang, Z., Ma, Q., & Zhang, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00268a · Cited by 1,348
Ultrathin metal-organic framework array for efficient electrocatalytic water splitting
Duan, J., Chen, S., & Zhao, C. (2017) · Nature Communications · doi:10.1038/ncomms15341 · Cited by 1,319
Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide
Cabán-Acevedo, M., Stone, M. L., Schmidt, J. R., Thomas, J. G., Ding, Q., Chang, H.-C., Tsai, M.-L., He, J.-H., & Jin, S. (2015) · Nature Materials · doi:10.1038/nmat4410 · Cited by 1,290
Ultrathin 2D Metal–Organic Framework Nanosheets
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Self-citationLattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis
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Cited by
Li, C., Xie, L., Zhao, J., Gu, L., Tang, H., Zheng, L., & Li, G. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202116934 · Cited by 396
Lin, L., Zhang, C., Liang, C., Zhang, H., Wang, Z., Wang, P., Zheng, Z., Cheng, H., Xing, D., Dai, Y., et al. (2024) · Advanced Materials · doi:10.1002/adma.202402388 · Cited by 77
Li, Y., Yuan, M., Yang, H., Shi, K., Sun, Z., Li, H., Nan, C., & Sun, G. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122167 · Cited by 55
Metadata
- Authors
- Ge, K., Sun, S., Zhao, Y., Yang, K., Wang, S., Zhang, Z., Cao, J., Yang, Y., Zhang, Y., Pan, M., & Zhu, L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-04-16
- Volume
- 60
- Issue
- 21
- Pages
- 12097-12102
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3134219571
- Cited by
- 398
- References
- 38
- FWCI
- 12.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ge, K., Sun, S., Zhao, Y., Yang, K., Wang, S., Zhang, Z., Cao, J., Yang, Y., Zhang, Y., Pan, M., & Zhu, L. (2021). Facile Synthesis of Two‐Dimensional Iron/Cobalt Metal–Organic Framework for Efficient Oxygen Evolution Electrocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202102632
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