Student or educator? Sign up with your school email and get 6 months of Pro free.
Cited by 1,290

The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.

Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide

Cabán-Acevedo, Miguel, Stone, Michael L., Schmidt, J. R., Thomas, Joseph G., Ding, Qi, Chang, Hung-Chih, Tsai, Meng-Lin, He, Jr-Hau, Jin, Song·2015·Nature Materials

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1038/nmat4410

Cites

13 of 13 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 13 references

Research works printed but not linked: 37

  1. Lewis, N. S. & Nocera, D. G. Powering the planet: Chemical challenges in solar energy utilization. Proc. Natl Acad. Sci. USA 103, 15729–15735 (2006). · DOI · Paper page
  2. Nocera, D. G. The artificial leaf. Acc. Chem. Res. 45, 767–776 (2012). · DOI · Paper page
  3. Turner, J. A. Sustainable hydrogen production. Science 305, 972–974 (2004). · DOI · Paper page
  4. Lukowski, M. A. et al. Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets. J. Am. Chem. Soc. 135, 10274–10277 (2013). · DOI · Paper page
  5. Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P. & Jaramillo, T. F. Catalyzing the Hydrogen Evolution Reaction (HER) with molybdenum sulfide nanomaterials. ACS Catal. 4, 3957–3971 (2014). · DOI · Paper page
  6. Merki, D., Fierro, S., Vrubel, H. & Hu, X. L. Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water. Chem. Sci. 2, 1262–1267 (2011). · DOI · Paper page
  7. Liu, Q. et al. Carbon nanotubes decorated with CoP nanocrystals: A highly active non-noble-metal nanohybrid electrocatalyst for hydrogen evolution. Angew. Chem. 126, 6828–6832 (2014). · DOI · Paper page
  8. Callejas, J. F. et al. Electrocatalytic and photocatalytic hydrogen production from acidic and neutral-pH aqueous solutions using iron phosphide nanoparticles. ACS Nano 8, 11101–11107 (2014). · DOI · Paper page
  9. Xiao, P. et al. Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction. Energy Environ. Sci. 7, 2624–2629 (2014). · DOI · Paper page
  10. McEnaney, J. M. et al. Amorphous molybdenum phosphide nanoparticles for electrocatalytic hydrogen evolution. Chem. Mater. 26, 4826–4831 (2014). · DOI · Paper page
  11. McKone, J. R., Lewis, N. S. & Gray, H. B. Will solar-driven water-splitting devices see the light of day? Chem. Mater. 26, 407–414 (2014). · DOI · Paper page
  12. Faber, M. S., Park, K., Cabán-Acevedo, M., Santra, P. K. & Jin, S. Earth-abundant cobalt pyrite (CoS2) thin film on glass as a robust, high-performance counter electrode for quantum dot-sensitized solar cells. J. Phys. Chem. Lett. 4, 1843–1849 (2013). · DOI · Paper page
  13. Faber, M. S., Lukowski, M. A., Ding, Q., Kaiser, N. S. & Jin, S. Earth-abundant metal pyrites (FeS2, CoS2, NiS2, and their alloys) for highly efficient hydrogen evolution and polysulfide reduction electrocatalysis. J. Phys. Chem. C 118, 21347–21356 (2014). · DOI · Paper page
  14. Cabán-Acevedo, M. et al. Ionization of high-density deep donor defect states explains the low photovoltage of iron pyrite single crystals. J. Am. Chem. Soc. 136, 17163–17179 (2014). · DOI
  15. Ennaoui, A. et al. Iron disulfide for solar energy conversion. Sol. Energy Mater. Sol. Cells 29, 289–370 (1993). · DOI · Paper page
  16. Stiebritz, M. T. & Reiher, M. A unifying structural and electronic concept for Hmd and [FeFe] hydrogenase active sites. Inorg. Chem. 49, 5818–5823 (2010). · doi:10.1021/ic902529c
  17. Thauer, R. K. et al. Hydrogenases from methanogenic archaea, nickel, a novel cofactor, and H2 storage. Annu. Rev. Biochem. 79, 507–536 (2010). · DOI · Paper page
  18. Kubas, G. J. Metal Dihydrogen and s-Bond Complexes: Structure, Theory, and Reactivity (Springer Science & Business Media, 2001). · DOI · Paper page
  19. Ishida, K. & Nishizawa, T. The Co–P (cobalt–phosphorus) system. Bull. Alloy Phase Diagr. 11, 555–560 (1990). · doi:10.1007/bf02841716
  20. Hulliger, F. New compounds with cobaltite structure. Nature 198, 382–383 (1963). · DOI
  21. Nørskov, J. K. et al. Trends in the exchange current for hydrogen evolution. J. Electrochem. Soc. 152, J23–J26 (2005). · DOI · Paper page
  22. Xia, X. et al. Controllable growth of conducting polymers shell for constructing high-quality organic/inorganic core/shell nanostructures and their optical–electrochemical properties. Nano Lett. 13, 4562–4568 (2013). · DOI · Paper page
  23. Lyapin, S. G. et al. Raman studies of nearly half-metallic ferromagnetic CoS2 . J. Phys. Condens. Matter 26, 396001 (2014). · DOI · Paper page
  24. Moulder, J. F., Stickle, W. F., Sobol, P. E. & Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer, 1992).
  25. Biesinger, M. C., Lau, L. W. M., Gerson, A. R. & Smart, R. S. C. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn. Appl. Surf. Sci. 257, 887–898 (2010). · DOI · Paper page
  26. Okamoto, H. P–S (phosphorus–sulfur). J. Phase Equilib. 12, 706–707 (1991).
  27. Dai, P. et al. Solar hydrogen generation by silicon nanowires modified with platinum nanoparticle catalysts by atomic layer deposition. Angew. Chem. Int. Ed. 52, 11119–11123 (2013). · DOI
  28. Boettcher, S. W. et al. Photoelectrochemical hydrogen evolution using Si microwire arrays. J. Am. Chem. Soc. 133, 1216–1219 (2011). · DOI · Paper page
  29. Wang, H.-P. et al. Realizing high-efficiency omnidirectional n-type Si solar cells via the hierarchical architecture concept with radial junctions. ACS Nano 7, 9325–9335 (2013). · DOI
  30. Kelzenberg, M. D. et al. Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications. Nature Mater. 9, 239–244 (2010). · DOI · Paper page
  31. Zhang, X. et al. Amorphous MoSxCly electrocatalyst supported by vertical graphene for efficient electrochemical and photoelectrochemical hydrogen generation. Energy Environ. Sci. 8, 862–868 (2015). · DOI · Paper page
  32. Ding, Q. et al. Efficient photoelectrochemical hydrogen generation using heterostructures of Si and chemically exfoliated metallic MoS2 . J. Am. Chem. Soc. 136, 8504–8507 (2014). · DOI · Paper page
  33. Huang, Z. et al. Ni12P5 nanoparticles as an efficient catalyst for hydrogen generation via electrolysis and photoelectrolysis. ACS Nano 8, 8121–8129 (2014). · DOI · Paper page
  34. Hou, Y. et al. Bioinspired molecular co-catalysts bonded to a silicon photocathode for solar hydrogen evolution. Nature Mater. 10, 434–438 (2011). · DOI · Paper page
  35. Benck, J. D. et al. Designing active and stable silicon photocathodes for solar hydrogen production using molybdenum sulfide nanomaterials. Adv. Energy Mater. 4, 1400739 (2014). · DOI · Paper page
  36. Kresse, G. & Hafner, J. Ab initio molecular-dynamics simulation of the liquid-metal-amorphous-semiconductor transition in germanium. Phys. Rev. B 49, 14251–14269 (1994). · DOI · Paper page
  37. Kresse, G. & Hafner, J. Ab initio molecular dynamics for liquid metals. Phys. Rev. B 47, 558–561 (1993). · DOI · Paper page

Cited by

See all 1,290

Metadata

Authors
Cabán-Acevedo, M., Stone, M. L., Schmidt, J. R., Thomas, J. G., Ding, Q., Chang, H.-C., Tsai, M.-L., He, J.-H., & Jin, S.
Venue
Nature Materials
Published
2015-09-14
Volume
14
Issue
12
Pages
1245-1251
ISSN
  • 1476-1122 (ISSN-L)
  • 1476-4660
OpenAlex
W1946340942
Cited by
1,290
References
13
FWCI
44.09
Type
journal article
Language
en
Open access
closed
Licence

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide. https://app.cochat.ai/papers/10.1038/nmat4410
The paper
Cabán-Acevedo, M., Stone, M. L., Schmidt, J. R., Thomas, J. G., Ding, Q., Chang, H.-C., Tsai, M.-L., He, J.-H., & Jin, S. (2015). Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide. Nature Materials. https://doi.org/10.1038/nmat4410

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.