The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Protonated Imine‐Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution
Open accessAbstract
Covalent organic frameworks (COFs) have emerged as an important class of organic semiconductors and photocatalysts for the hydrogen evolution reaction (HER)from water. To optimize their photocatalytic activity, typically the organic moieties constituting the frameworks are considered and the most suitable combinations of them are searched for. However, the effect of the covalent linkage between these moieties on the photocatalytic performance has rarely been studied. Herein, we demonstrate that donor‐acceptor (D‐A) type imine‐linked COFs can produce hydrogen with a rate as high as 20.7 mmol g−1 h−1 under visible light irradiation, upon protonation of their imine linkages. A significant red‐shift in light absorbance, largely improved charge separation efficiency, and an increase in hydrophilicity triggered by protonation of the Schiff‐base moieties in the imine‐linked COFs, are responsible for the improved photocatalytic performance.
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Cites
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
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Self-citationThe atom, the molecule, and the covalent organic framework
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Covalent Organic Frameworks: Chemistry beyond the Structure
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Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
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A tunable azine covalent organic framework platform for visible light-induced hydrogen generation
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Cited by
Molecularly Engineered Covalent Organic Frameworks for Hydrogen Peroxide Photosynthesis
Kou, M., Wang, Y., Xu, Y., Ye, L., Huang, Y., Jia, B., Li, H., Ren, J., Deng, Y., Chen, J., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202200413 · Cited by 697
Guo, Y., Zhou, Q., Nan, J., Shi, W., Cui, F., & Zhu, Y. (2022) · Nature Communications · doi:10.1038/s41467-022-29826-z · Cited by 284
Yang, J., Ghosh, S., Roeser, J., Acharjya, A., Penschke, C., Tsutsui, Y., Rabeah, J., Wang, T., Djoko Tameu, S. Y., Ye, M.-Y., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-33875-9 · Cited by 279
Self-citationLiu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Yang, J., Acharjya, A., Ye, M., Rabeah, J., Li, S., Kochovski, Z., Youk, S., Roeser, J., Grüneberg, J., Penschke, C., Schwarze, M., Wang, T., Lu, Y., van de Krol, R., Oschatz, M., Schomäcker, R., Saalfrank, P., & Thomas, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-07-26
- Volume
- 60
- Issue
- 36
- Pages
- 19797-19803
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3165523086
- Cited by
- 444
- References
- 37
- FWCI
- 18.95
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Yang, J., Acharjya, A., Ye, M., Rabeah, J., Li, S., Kochovski, Z., Youk, S., Roeser, J., Grüneberg, J., Penschke, C., Schwarze, M., Wang, T., Lu, Y., van de Krol, R., Oschatz, M., Schomäcker, R., Saalfrank, P., & Thomas, A. (2021). Protonated Imine‐Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202104870
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