The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Phosphorus Induced Electron Localization of Single Iron Sites for Boosted CO2 Electroreduction Reaction
Open accessAbstract
Electrochemical reduction of carbon dioxide (CO 2) into chemicals and fuels has recently attracted much interest, but normally suffers from a high overpotential and low selectivity. In this work, single P atoms were introduced into a N‐doped carbon supported single Fe atom catalyst (Fe‐SAC/NPC) mainly in the form of P−C bonds for CO 2 electroreduction to CO in an aqueous solution. This catalyst exhibited a CO Faradaic efficiency of ≈97 % at a low overpotential of 320 mV, and a Tafel slope of only 59 mV dec−1, comparable to state‐of‐the‐art gold catalysts. Experimental analysis combined with DFT calculations suggested that single P atom in high coordination shells (n≥3), in particular the third coordination shell of Fe center enhanced the electronic localization of Fe, which improved the stabilization of the key *COOH intermediate on Fe, leading to superior CO 2 electrochemical reduction performance at low overpotentials.
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Cites
Domino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Selective increase in CO 2 electroreduction activity at grain-boundary surface terminations
Mariano, R. G., McKelvey, K., White, H. S., & Kanan, M. W. (2017) · Science · doi:10.1126/science.aao3691 · Cited by 818
Back, S., Lim, J., Kim, N.-Y., Kim, Y.-H., & Jung, Y. (2017) · Chemical Science · doi:10.1039/c6sc03911a · Cited by 542
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Self-citationZhang, J., & Dai, L. (2016) · Angewandte Chemie · doi:10.1002/ange.201607405 · Cited by 129
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Cited by
Cui, T., Wang, Y., Ye, T., Wu, J., Chen, Z., Li, J., Lei, Y., Wang, D., & Li, Y. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202115219 · Cited by 659
Self-citationUnderstanding the structure-performance relationship of active sites at atomic scale
Li, R., & Wang, D. (2022) · Nano Research · doi:10.1007/s12274-022-4371-x · Cited by 537
Self-citationJing, H., Zhu, P., Zheng, X., Zhang, Z., Wang, D., & Li, Y. (2022) · Advanced Powder Materials · doi:10.1016/j.apmate.2021.10.004 · Cited by 406
Self-citationZhu, P., Xiong, X., & Wang, D. (2022) · Nano Research · doi:10.1007/s12274-022-4265-y · Cited by 375
Self-citationMicroenvironment Engineering of Single/Dual‐Atom Catalysts for Electrocatalytic Application
Gao, Y., Liu, B., & Wang, D. (2023) · Advanced Materials · doi:10.1002/adma.202209654 · Cited by 319
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Metadata
- Authors
- Sun, X., Tuo, Y., Ye, C., Chen, C., Lu, Q., Li, G., Jiang, P., Chen, S., Zhu, P., Ma, M., Zhang, J., Bitter, J. H., Wang, D., & Li, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-10
- Volume
- 60
- Issue
- 44
- Pages
- 23614-23618
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3197689157
- Cited by
- 315
- References
- 6
- FWCI
- 10.86
- Type
- journal article
- Language
- en
- Open access
- green
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- Sun, X., Tuo, Y., Ye, C., Chen, C., Lu, Q., Li, G., Jiang, P., Chen, S., Zhu, P., Ma, M., Zhang, J., Bitter, J. H., Wang, D., & Li, Y. (2021). Phosphorus Induced Electron Localization of Single Iron Sites for Boosted CO2 Electroreduction Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202110433
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