Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide‐Derived Nanostructured Silver Electrocatalysts
Open accessAbstract
In this work, the selective electrocatalytic reduction of carbon dioxide to carbon monoxide on oxide‐derived silver electrocatalysts is presented. By a simple synthesis technique, the overall high faradaic efficiency for CO production on the oxide‐derived Ag was shifted by more than 400 mV towards a lower overpotential compared to that of untreated Ag. Notably, the Ag resulting from Ag oxide is capable of electrochemically reducing CO 2 to CO with approximately 80 % catalytic selectivity at a moderate overpotential of 0.49 V, which is much higher than that (ca. 4 %) of untreated Ag under identical conditions. Electrokinetic studies show that the improved catalytic activity is ascribed to the enhanced stabilization of COOH . intermediate. Furthermore, highly nanostructured Ag is likely able to create a high local pH near the catalyst surface, which may also facilitate the catalytic activity for the reduction of CO 2 with suppressed H 2 evolution.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The text we found for this paper looks like another document, so the self-check wasn’t run.
Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784 · see citing works
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
Kortlever, R., Shen, J., Schouten, K. J. P., Calle‐Vallejo, F., & Koper, M. T. M. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01559 · Cited by 2,183 · see citing works
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140 · see citing works
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000 · see citing works
Electrochemical CO2 Reduction on Metal Electrodes
Hori, Y. (2008) · Springer eBooks · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,904 · see citing works
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728 · see citing works
Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,671 · see citing works
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661 · see citing works
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649 · see citing works
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,499 · see citing works
A selective and efficient electrocatalyst for carbon dioxide reduction
Lu, Q., Rosen, J., Zhou, Y., Hutchings, G. S., Kimmel, Y. C., Chen, J. G., & Jiao, F. (2014) · Nature Communications · doi:10.1038/ncomms4242 · Cited by 1,474 · see citing works
Prospects of CO 2 Utilization via Direct Heterogeneous Electrochemical Reduction
Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,419 · see citing works
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,157 · see citing works
Chen, Y., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108799 · Cited by 982 · see citing works
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941 · see citing works
Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601582 · Cited by 896 · see citing works
Electrochemical Reduction of CO at a Copper Electrode
Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970284i · Cited by 818 · see citing works
Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO 2 Reduction to CO
Hansen, H. A., Varley, J. B., Peterson, A. A., & Nørskov, J. K. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz3021155 · Cited by 753 · see citing works
Grain-Boundary-Dependent CO <sub>2</sub> Electroreduction Activity
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5130513 · Cited by 694 · see citing works
Zhang, S., Kang, P., Ubnoske, S. M., Brennaman, M. K., Song, N., House, R. L., Glass, J. T., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5031529 · Cited by 659 · see citing works
Ma, M., Djanashvili, K., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601282 · Cited by 640 · see citing works
Self-citationMechanistic Insights into the Electrochemical Reduction of CO2 to CO on Nanostructured Ag Surfaces
Rosen, J., Hutchings, G. S., Lu, Q., Rivera, S., Zhou, Y., Vlachos, D. G., & Jiao, F. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00840 · Cited by 605 · see citing works
Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
Manthiram, K., Beberwyck, B. J., & Alivisatos, A. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5065284 · Cited by 546 · see citing works
Rasul, S., Anjum, D. H., Jedidi, A., Minenkov, Y. V., Cavallo, L., & Takanabe, K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201410233 · Cited by 512 · see citing works
Hoflund, G. B., Hazos, Z. F., & Salaita, G. N. (2000) · Physical review. B, Condensed matter · doi:10.1103/physrevb.62.11126 · Cited by 411 · see citing works
Kaş, R., Hummadi, K. K., Kortlever, R., de Wit, P., Milbrat, A., Luiten-Olieman, M. W. J., Benes, N. E., Koper, M. T. M., & Mul, G. (2016) · Nature Communications · doi:10.1038/ncomms10748 · Cited by 366 · see citing works
Controlling H + vs CO 2 Reduction Selectivity on Pb Electrodes
Lee, C. H., & Kanan, M. W. (2014) · ACS Catalysis · doi:10.1021/cs5017672 · Cited by 341 · see citing works
Torelli, D. A., Francis, S. A., Crompton, J. C., Javier, A., Thompson, J. R., Brunschwig, B. S., Soriaga, M. P., & Lewis, N. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02888 · Cited by 306 · see citing works
Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction
Lu, Q., Rosen, J., & Jiao, F. (2014) · ChemCatChem · doi:10.1002/cctc.201402669 · Cited by 269 · see citing works
Theoretical Considerations on the Electroreduction of CO to C2 Species on Cu(100) Electrodes
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie · doi:10.1002/ange.201301470 · Cited by 239 · see citing works
Study of structure and optical properties of silver oxide films by ellipsometry, XRD and XPS methods
Gao, X.-Y., Wang, S., Li, J., Zheng, Y.-X., Zhang, R., Zhou, P., Yang, Y.-M., & Chen, L. (2004) · Thin Solid Films · doi:10.1016/j.tsf.2003.11.242 · Cited by 222 · see citing works
Selective electrochemical reduction of CO 2 to CO on CuO-derived Cu nanowires
Ma, M., Djanashvili, K., & Smith, W. A. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03559g · Cited by 182 · see citing works
Self-citationRasul, S., Anjum, D. H., Jedidi, A., Minenkov, Y. V., Cavallo, L., & Takanabe, K. (2014) · Angewandte Chemie · doi:10.1002/ange.201410233 · Cited by 144 · see citing works
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO2 over Cu Nanowire Arrays
Ma, M., Djanashvili, K., & Smith, W. A. (2016) · Angewandte Chemie · doi:10.1002/ange.201601282 · Cited by 121 · see citing works
Self-citationTailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie · doi:10.1002/ange.201601582 · Cited by 111 · see citing works
Tamura, J., Ono, A., Sugano, Y., Huang, C., Nishizawa, H., & Mikoshiba, S. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03028e · Cited by 100 · see citing works
Electrochemical formation and reduction of silver oxides in alkaline media
Droog, J. M. M., & Huisman, F. (1980) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(80)80326-3 · Cited by 86 · see citing works
The electrochemical formation of Ag2O in KOH electrolyte
Ambrose, J., & Barradas, R. G. (1974) · Electrochimica Acta · doi:10.1016/0013-4686(74)80023-x · Cited by 61 · see citing works
Becerra, J. G., Salvarezza, R. C., & Arvia, A. J. (1988) · Electrochimica Acta · doi:10.1016/0013-4686(88)80135-x · Cited by 52 · see citing works
Maurice, V., Klein, L. H., Strehblow, H., & Marcus, P. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp0742517 · Cited by 39 · see citing works
A potentiostatic study of the electrolytic formation of AgO
Dirkse, T. P. (1990) · Electrochimica Acta · doi:10.1016/0013-4686(90)85019-j · Cited by 31 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747 · see citing works
Cocatalysts for Selective Photoreduction of CO 2 into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,306 · see citing works
Zhao, C., Dai, X., Yao, T., Chen, W., Wang, X., Wang, J., Yang, J., Wei, S., Wu, Y. S., & Li, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02736 · Cited by 1,361 · see citing works
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works
Electrocatalysis for CO <sub>2</sub> conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295 · see citing works
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts
Francke, R., Schille, B., & Roemelt, M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00459 · Cited by 1,165 · see citing works
Burdyny, T., & Smith, W. A. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03134g · Cited by 1,147 · see citing works
Self-citationElectrochemical CO 2 Reduction: A Classification Problem
Bagger, A., Ju, W., Varela, A. S., Strasser, P., & Rossmeisl, J. (2017) · ChemPhysChem · doi:10.1002/cphc.201700736 · Cited by 1,075 · see citing works
Isolated Ni single atoms in graphene nanosheets for high-performance CO 2 reduction
Jiang, K. P., Siahrostami, S., Zheng, T., Hu, Y., Hwang, S., Stavitski, E., Peng, Y., Dynes, J. J., Gangisetty, M., Su, D., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03245e · Cited by 1,026 · see citing works
Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101818 · Cited by 1,027 · see citing works
Zhang, W., Hu, Y. T., Ma, L., Zhu, G., Wang, Y., Xue, X., Chen, R., Yang, S., & Jin, Z. (2017) · Advanced Science · doi:10.1002/advs.201700275 · Cited by 948 · see citing works
Molecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell
Ren, S., Joulié, D., Salvatore, D. A., Torbensen, K., Wang, M., Robert, M., & Berlinguette, C. P. (2019) · Science · doi:10.1126/science.aax4608 · Cited by 944 · see citing works
CO 2 Reduction: From the Electrochemical to Photochemical Approach
Wu, J., Huang, Y., Ye, W., & Li, Y. (2017) · Advanced Science · doi:10.1002/advs.201700194 · Cited by 940 · see citing works
Surface and Interface Control in Nanoparticle Catalysis
Xie, C., Niu, Z., Kim, D., Li, M., & Yang, P. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00220 · Cited by 869 · see citing works
Low-dimensional catalysts for hydrogen evolution and CO2 reduction
Voiry, D., Shin, H. S., Loh, K. P., & Chhowalla, M. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0105 · Cited by 850 · see citing works
Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction
Chen, C., Kotyk, J. F. K., & Sheehan, S. W. (2018) · Chem · doi:10.1016/j.chempr.2018.08.019 · Cited by 763 · see citing works
Gong, Q., Ding, P., Xu, M., Zhu, X., Wang, M., Deng, J., Ma, Q., Han, N., Zhu, Y. S., Lu, J. B., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10819-4 · Cited by 679 · see citing works
Defect and Interface Engineering for Aqueous Electrocatalytic CO2 Reduction
Wang, Y., Han, P., Lv, X., Zhang, L., & Zheng, G. (2018) · Joule · doi:10.1016/j.joule.2018.09.021 · Cited by 675 · see citing works
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 631 · see citing works
Cheng, Y., Zhao, S., Johannessen, B., Veder, J., Saunders, M., Rowles, M. R., Cheng, H., Liu, C., Chisholm, M. F., MARCO, R. D., et al. (2018) · Advanced Materials · doi:10.1002/adma.201706287 · Cited by 613 · see citing works
Recent Advances in Electrochemical CO 2 ‐to‐CO Conversion on Heterogeneous Catalysts
Zheng, T., Jiang, K., & Wang, H. (2018) · Advanced Materials · doi:10.1002/adma.201802066 · Cited by 582 · see citing works
Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521 · see citing works
Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 482 · see citing works
High-Entropy Alloys as Catalysts for the CO 2 and CO Reduction Reactions: Experimental Realization
Nellaiappan, S., Katiyar, N. K., Kumar, R., Parui, A., Malviya, K. D., Pradeep, K. G., Singh, A. K., Sharma, S., Tiwary, C. S., & Biswas, K. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b04302 · Cited by 453 · see citing works
Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer
Leonard, M. E., Clarke, L. E., Forner‐Cuenca, A., Brown, S. M., & Brushett, F. R. (2019) · ChemSusChem · doi:10.1002/cssc.201902547 · Cited by 375 · see citing works
Boosting CO Production in Electrocatalytic CO2 Reduction on Highly Porous Zn Catalysts
Luo, W., Zhang, J., Li, M., & Züttel, A. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b05109 · Cited by 364 · see citing works
Zhao, S., Jin, R., & Jin, R. M. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01104 · Cited by 368 · see citing works
High Rate, Selective, and Stable Electroreduction of CO 2 to CO in Basic and Neutral Media
Dinh, C., de Arquer, F. P. G., Sinton, D. A., & Sargent, E. H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01734 · Cited by 349 · see citing works
Manganese acting as a high-performance heterogeneous electrocatalyst in carbon dioxide reduction
Zhang, B., Zhang, J., Shi, J., Tan, D., Liu, L., Zhang, F., Su, Z., Su, Z., Tan, X., Cheng, X., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10854-1 · Cited by 341 · see citing works
Pan, Y., Zhang, C., Liu, Z., Chen, C., & Li, Y. (2020) · Matter · doi:10.1016/j.matt.2019.11.014 · Cited by 345 · see citing works
Hu, X., Hval, H. H., Bjerglund, E. T., Dalgaard, K. J., Madsen, M. R., Pohl, M., Welter, E., Lamagni, P., Buhl, K. B., Bremholm, M., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01022 · Cited by 343 · see citing works
Pan, F., Deng, W., Justiniano, C., & Li, Y. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.01.001 · Cited by 341 · see citing works
Activation of Ni Particles into Single Ni–N Atoms for Efficient Electrochemical Reduction of CO2
Fan, Q., Hou, P., Choi, C., Wu, T., Hong, S. K., Li, F., Soo, Y. L., Kang, P., Jung, Y., & Sun, Z. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201903068 · Cited by 329 · see citing works
Electrocatalytic carbon dioxide reduction: from fundamental principles to catalyst design
Zhang, X., Guo, S., Gandionco, K. A., Bond, A. M., & Zhang, J. (2020) · Materials Today Advances · doi:10.1016/j.mtadv.2020.100074 · Cited by 328 · see citing works
Electrocatalytic Alloys for CO2 Reduction
He, J., Johnson, N. J. J., Huang, A., & Berlinguette, C. P. (2017) · ChemSusChem · doi:10.1002/cssc.201701825 · Cited by 321 · see citing works
Cheng, Y., Zhao, S., Li, H., He, S., Veder, J., Johannessen, B., Xiao, J., Lu, S., Pan, J., Chisholm, M. F., et al. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.10.046 · Cited by 321 · see citing works
Sun, X., Tuo, Y., Ye, C., Chen, C., Lü, Q., Li, G., Jiang, P., Chen, S., Zhu, P., Ma, M., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202110433 · Cited by 314 · see citing works
Self-citationHuang, N., Lee, K. H., Yue, Y., Xu, X., Irle, S., Jiang, Q., & Jiang, D. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202005274 · Cited by 312 · see citing works
Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels
Yoon, Y., Hall, A. S., & Surendranath, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201607942 · Cited by 310 · see citing works
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y. N., Wang, M., Wu, C., Zhang, L., Xiao, L., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 305 · see citing works
Khan, K., Tareen, A. K., Aslam, M., Zhang, Y., Wang, R., Ouyang, Z., Gou, Z., & Zhang, H. (2019) · Nanoscale · doi:10.1039/c9nr05919a · Cited by 304 · see citing works
Fan, K., Jia, Y., Ji, Y., Kuang, P., Zhu, B., Liu, X., & Yu, J. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b04516 · Cited by 300 · see citing works
Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts
Liu, A., Gao, M., Ren, X., Meng, F., Yang, Y., Gao, L., Yang, Q., & Ma, T. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta11966c · Cited by 289 · see citing works
Efficient electrocatalytic conversion of carbon monoxide to propanol using fragmented copper
Pang, Y., Li, J., Wang, Z., Tan, C., Hsieh, P., Zhuang, T., Liang, Z.-Q., Zou, C., Wang, X., Luna, P. D., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0225-7 · Cited by 292 · see citing works
In Situ Fragmented Bismuth Nanoparticles for Electrocatalytic Nitrogen Reduction
Yao, D., Tang, C., Li, L., Xia, B., Vasileff, A., Jin, H., Zhang, Y., & Qiao, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001289 · Cited by 283 · see citing works
Andrei, V., Reuillard, B., & Reisner, E. (2019) · Nature Materials · doi:10.1038/s41563-019-0501-6 · Cited by 282 · see citing works
Electrolyte Effects on the Electrochemical Reduction of CO2
Pupo, M. M. D. S., & Kortlever, R. (2019) · ChemPhysChem · doi:10.1002/cphc.201900680 · Cited by 277 · see citing works
Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie · doi:10.1002/ange.202101818 · Cited by 268 · see citing works
pH Matters When Reducing CO 2 in an Electrochemical Flow Cell
Zhang, Z. B., Melo, L., Jansonius, R. P., Habibzadeh, F., Grant, E. R., & Berlinguette, C. P. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c01606 · Cited by 269 · see citing works
Two-dimensional nanosheets for electrocatalysis in energy generation and conversion
Tao, H., Gao, Y., Talreja, N., Guo, F., Texter, J. A., Yan, C., & Sun, Z. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta00075h · Cited by 261 · see citing works
Ye, L., Ying, Y., Sun, D., Zhang, Z., Fei, L., Wen, Z., Qiao, J., & Huang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201912751 · Cited by 254 · see citing works
CO 2 reduction: the quest for electrocatalytic materials
Khezri, B., Fisher, A. C., & Pumera, M. (2017) · Journal of Materials Chemistry A · doi:10.1039/c6ta09875d · Cited by 254 · see citing works
Gu, J., Héroguel, F., Luterbacher, J. S., & Hu, X. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201713003 · Cited by 253 · see citing works
Bohra, D., Chaudhry, J. H., Burdyny, T., Pidko, E. A., & Smith, W. A. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02485a · Cited by 242 · see citing works
Self-citationTuning of CO<sub>2</sub> Reduction Selectivity on Metal Electrocatalysts
Wang, Y., Liu, J., Wang, Y., Al‐Enizi, A. M., & Zheng, G. (2017) · Small · doi:10.1002/smll.201701809 · Cited by 241 · see citing works
Mistry, H., Choi, Y., Bagger, A., Scholten, F., Bonifacio, C. S., Sinev, I., Divins, N. J., Zegkinoglou, I., Jeon, H. S., Kisslinger, K., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704613 · Cited by 233 · see citing works
Selective and Stable Electroreduction of CO2 to CO at the Copper/Indium Interface
Luo, W., Xie, W., Mutschler, R., Oveisi, E., Gregorio, G. L. D., Buonsanti, R., & Züttel, A. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04457 · Cited by 222 · see citing works
Yu, S., Wilson, A. J., Kumari, G., Zhang, X., & Jain, P. K. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00640 · Cited by 221 · see citing works
O’Mara, P. B., Wilde, P., Benedetti, T. M., Andronescu, C., Cheong, S., Gooding, J. J., Tilley, R. D., & Schuhmann, W. W. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07310 · Cited by 219 · see citing works
Jeong, H., Balamurugan, M., Choutipalli, V. S. K., Jeong, E., Subramanian, V., Sim, U., & Nam, K. T. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta02405k · Cited by 210 · see citing works
Firet, N. J., Blommaert, M. A., Burdyny, T., Venugopal, A., Bohra, D., Longo, A., & Smith, W. A. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta10412c · Cited by 206 · see citing works
Self-citationRational Design of Ag‐Based Catalysts for the Electrochemical CO2 Reduction to CO: A Review
Sun, D., Xu, X., Qin, Y., Jiang, S. P., & Shao, Z. (2019) · ChemSusChem · doi:10.1002/cssc.201902061 · Cited by 203 · see citing works
Electrochemical reconstruction of ZnO for selective reduction of CO2 to CO
Luo, W., Zhang, Q., Zhang, J., Moioli, E., Zhao, K., & Züttel, A. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119060 · Cited by 192 · see citing works
Yao, D., Tang, C., Zhi, X., Johannessen, B., Slattery, A. D., Chern, S., & Qiao, S. (2022) · Advanced Materials · doi:10.1002/adma.202209386 · Cited by 195 · see citing works
Huang, W., Zhu, J., Wang, M., Hu, L., Tang, Y., Shu, Y., Xie, Z., & Zhang, H. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202007584 · Cited by 195 · see citing works
Ligand Engineering in Nickel Phthalocyanine to Boost the Electrocatalytic Reduction of CO2
Chen, K., Cao, M., Lin, Y., Fu, J., Liao, H., Zhou, Y., Li, H., Qiu, X., Hu, J., Zheng, X., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202111322 · Cited by 194 · see citing works
Ma, M., Liu, K., Shen, J., Kaş, R., & Smith, W. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00472 · Cited by 189 · see citing works
Self-citationClark, E. L., Ringe, S., Tang, M. T., Walton, A., Hahn, C., Jaramillo, T. F., Chan, K., & Bell, A. T. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00260 · Cited by 190 · see citing works
Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts
Tufa, R. A., Chanda, D., Ma, M., Aili, D., Demissie, T. B., Vaes, J., Li, Q., Liu, S., & Pant, D. (2020) · Applied Energy · doi:10.1016/j.apenergy.2020.115557 · Cited by 191 · see citing works
Self-citationIdentification of Single-Atom Ni Site Active toward Electrochemical CO 2 Conversion to CO
Kim, H., Shin, D., Yang, W., Won, D. H., Oh, H., Chung, M. W., Jeong, D., Kim, S. H., Chae, K. H., Ryu, J. Y., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c11008 · Cited by 189 · see citing works
Synergistic Electrochemical CO2 Reduction and Water Oxidation with a Bipolar Membrane
Vermaas, D. A., & Smith, W. A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00557 · Cited by 187 · see citing works
Self-citationQin, B., Li, Y., Fu, H., Wang, H., Chen, S., Liu, Z., & Peng, F. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b04809 · Cited by 185 · see citing works
P-block metal-based (Sn, In, Bi, Pb) electrocatalysts for selective reduction of CO2 to formate
Yang, Z., Oropeza, F. E., & Zhang, K. H. L. (2020) · APL Materials · doi:10.1063/5.0004194 · Cited by 188 · see citing works
He, R. L., Zhang, A., Ding, Y., Kong, T., Xiao, Q., Li, H., Liu, Y., & Zeng, J. (2018) · Advanced Materials · doi:10.1002/adma.201705872 · Cited by 184 · see citing works
Phase-Selective Epitaxial Growth of Heterophase Nanostructures on Unconventional 2H-Pd Nanoparticles
Ge, Y., Huang, Z., Ling, C., Chen, B., Liu, G., Zhou, M. Y., Liu, J., Zhang, X., Cheng, H., Liu, G., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c09461 · Cited by 183 · see citing works
Tandem catalysis in electrochemical CO2 reduction reaction
Zhu, Y., Cui, X., Liu, H., Guo, Z., Dang, Y., Fan, Z., Zhang, Z., & Hu, W. (2021) · Nano Research · doi:10.1007/s12274-021-3448-2 · Cited by 182 · see citing works
Chen, Y., Vise, A. E., Klein, W. E., Cetinbas, F. C., Myers, D. J., Smith, W. A., Deutsch, T. G., & Neyerlin, K. C. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00860 · Cited by 178 · see citing works
Self-citationLu, Y., Zhang, Z., Wang, H., & Wang, Y. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120162 · Cited by 172 · see citing works
Daiyan, R., Saputera, W. H., Masood, H., Leverett, J., Lu, X., & Amal, R. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902106 · Cited by 172 · see citing works
Ma, Y., Wang, J., Yu, J., Zhou, J., Zhou, X., Li, H., He, Z., Long, H., Wang, Y., Lu, P., et al. (2021) · Matter · doi:10.1016/j.matt.2021.01.007 · Cited by 172 · see citing works
Bagger, A., Ju, W., Varela, A. S., Strasser, P., & Rossmeisl, J. (2017) · Catalysis Today · doi:10.1016/j.cattod.2017.02.028 · Cited by 168 · see citing works
Catalysts in electro-, photo- and photoelectrocatalytic CO2 reduction reactions
Wang, Y., He, D., Chen, H., & Wang, D. (2019) · Journal of Photochemistry and Photobiology C Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2019.02.002 · Cited by 164 · see citing works
Progress in development of electrocatalyst for CO2 conversion to selective CO production
Nguyen, D. L. T., Kim, Y., Hwang, Y. J., & Won, D. H. (2019) · Carbon Energy · doi:10.1002/cey2.27 · Cited by 164 · see citing works
Feng, Y., Li, Z., Liu, H., Dong, C., Wang, J., Kulinich, S. A., & Du, X. (2018) · Langmuir · doi:10.1021/acs.langmuir.8b02837 · Cited by 164 · see citing works
Ma, M., Kim, S.-K., Chorkendorff, I., & Seger, B. J. (2020) · Chemical Science · doi:10.1039/d0sc03047c · Cited by 165 · see citing works
Self-citationCO2 electrochemical reduction: A state-of-the-art review with economic and environmental analyses
Leonzio, G., Hankin, A., & Shah, N. (2024) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2024.07.014 · Cited by 169 · see citing works
3D hierarchical porous indium catalyst for highly efficient electroreduction of CO 2
Luo, W., Xie, W., Li, M., Zhang, J., & Züttel, A. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11645h · Cited by 161 · see citing works
Wu, X., Guo, Y., Sun, Z., Xie, F., Guan, D., Dai, J., Yu, F., Hu, Z., Huang, Y., Pao, C., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-20960-8 · Cited by 162 · see citing works
Zhang, W., Jin, Z., & Chen, Z. (2022) · Advanced Science · doi:10.1002/advs.202105204 · Cited by 160 · see citing works
Pan, F., Li, B., Sarnello, E., Hwang, S., Gang, Y., Feng, X., Xiang, X., Adli, N. M., Li, T., Su, D., et al. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.104384 · Cited by 160 · see citing works
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie · doi:10.1002/ange.201608279 · Cited by 152 · see citing works
Molecular tuning for electrochemical CO2 reduction
Zhang, J., Ding, J., Liu, Y., Su, C., Yang, H., Huang, Y., & Liu, B. (2023) · Joule · doi:10.1016/j.joule.2023.07.010 · Cited by 152 · see citing works
Lee, C. W., Cho, N. H., Im, S. W., Jee, M. S., Hwang, Y. J., Min, B. K., & Nam, K. T. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta03480j · Cited by 150 · see citing works
Chen, Z., Fan, T., Zhang, Y., Xiao, J., Gao, M., Duan, N., Zhang, J., Li, J., Liu, Q., Yi, X., et al. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118243 · Cited by 150 · see citing works
Li Electrochemical Tuning of Metal Oxide for Highly Selective CO2 Reduction
Jiang, K. P., Wang, H., Cai, W., & Wang, H. (2017) · ACS Nano · doi:10.1021/acsnano.7b03029 · Cited by 147 · see citing works
Zang, D., Li, Q., Dai, G., Zeng, M., Huang, Y., & Wei, Y. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119426 · Cited by 148 · see citing works
Unraveling Structure Sensitivity in CO 2 Electroreduction to Near-Unity CO on Silver Nanocubes
Liu, S., Sun, C., Xiao, J., & Luo, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b03883 · Cited by 146 · see citing works
Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO 2 Electrochemical Reduction
Wang, R., Sun, X., Ould‐Chikh, S., Osadchii, D., Bai, F., Kapteijn, F., & Gascón, J. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b02226 · Cited by 143 · see citing works
Bohra, D., Ledezma‐Yanez, I., Li, G., de Jong, W., Pidko, E. A., & Smith, W. A. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201811667 · Cited by 143 · see citing works
Self-citationUrbain, F., Tang, P., Carretero, N. M., Andreu, T., Gerling, L. G., Voz, C., Arbiol, J., & Morante, J. R. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01747b · Cited by 142 · see citing works
- Authors
- Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A.
- Affiliations
- China University of Petroleum, East China (CN)
- Delft University of Technology (NL)
- Eindhoven University of Technology (NL)
- Corresponding author
- Smith, Wilson A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-07-05
- Volume
- 55
- Issue
- 33
- Pages
- 9748-9752
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2470317005
- Cited by
- 530
- References
- 43
- Citations by year
- 2026: 17 · 2025: 34 · 2024: 49 · 2023: 50 · 2022: 43 · 2021: 72 · 2020: 81 · 2019: 78 · 2018: 62 · 2017: 38 · 2016: 6
- FWCI
- 16.65
- Type
- journal article
- Language
- en
- Open access
- green
- research.tue.nl
- Licence
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- TU/e Research Portal (publishedVersion, other-oa)
- TU/e Research Portal (submittedVersion)
- TU/e Research Portal (submittedVersion, other-oa)
- Funders
- CSC
- NWO VENI
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, carbon monoxide production, silver electrocatalyst, silver nanostructures, COOH intermediate, Faradaic efficiency, overpotential, local pH, hydrogen evolution suppression, CO selectivity
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review