The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Highly Ethylene‐Selective Electrocatalytic CO2 Reduction Enabled by Isolated Cu−S Motifs in Metal–Organic Framework Based Precatalysts
Open accessAbstract
Copper‐based materials are efficient electrocatalysts for the conversion of CO 2 to C 2+ products, and most these materials are reconstructed in situ to regenerate active species. It is a challenge to precisely design precatalysts to obtain active sites for the CO 2 reduction reaction (CO 2 RR). Herein, we develop a strategy based on local sulfur doping of a Cu‐based metal–organic framework precatalyst, in which the stable Cu−S motif is dispersed in the framework of HKUST‐1 (S‐HKUST‐1). The precatalyst exhibits a high ethylene selectivity in an H‐type cell with a maximum faradaic efficiency (FE) of 60.0 %, and delivers a current density of 400 mA cm−2 with an ethylene FE up to 57.2 % in a flow cell. Operando X‐ray absorption results demonstrate that Cu δ+ species stabilized by the Cu−S motif exist in S‐HKUST‐1 during CO 2 RR. Density functional theory calculations indicate the partially oxidized Cu δ+ at the Cu/CuxSy interface is favorable for coupling of the *CO intermediate due to the modest distance between coupling sites and optimized adsorption energy.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2
Liang, Z.-Q., Zhuang, T.-T., Seifitokaldani, A., Li, J., Huang, C.-W., Tan, C.-S., Li, Y., De Luna, P., Dinh, C. T., Hu, Y., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-06311-0 · Cited by 393
Cited by
Chang, B., Pang, H., Raziq, F., Wang, S., Huang, K.-W., Ye, J., & Zhang, H. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00964e · Cited by 458
Metadata
- Authors
- Wen, C. F., Zhou, M., Liu, P. F., Liu, Y., Wu, X., Mao, F., Dai, S., Xu, B., Wang, X. L., Jiang, Z., Hu, P., Yang, S., Wang, H. F., & Yang, H. G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-12-02
- Volume
- 61
- Issue
- 2
- Pages
- e202111700-e202111700
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3206365980
- Cited by
- 206
- References
- 8
- FWCI
- 5.99
- Type
- journal article
- Language
- en
- Open access
- green
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- Wen, C. F., Zhou, M., Liu, P. F., Liu, Y., Wu, X., Mao, F., Dai, S., Xu, B., Wang, X. L., Jiang, Z., Hu, P., Yang, S., Wang, H. F., & Yang, H. G. (2022). Highly Ethylene‐Selective Electrocatalytic CO2 Reduction Enabled by Isolated Cu−S Motifs in Metal–Organic Framework Based Precatalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202111700
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