The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Clusters Induced Electron Redistribution to Tune Oxygen Reduction Activity of Transition Metal Single‐Atom for Metal–Air Batteries
Abstract
Oxygen reduction reaction (ORR) activity can be effectively tuned by modulating the electron configuration and optimizing the chemical bonds. Herein, a general strategy to optimize the activity of metal single‐atoms is achieved by the decoration of metal clusters via a coating–pyrolysis–etching route. In this unique structure, the metal clusters are able to induce electron redistribution and modulate M−N species bond lengths. As a result, M‐ACSA@NC exhibits superior ORR activity compared with the nanoparticle‐decorated counterparts. The performance enhancement is attributed to the optimized intermediates desorption benefiting from the unique electronic configuration. Theoretical analysis reinforces the significant roles of metal clusters by correlating the ORR activity with cluster‐induced charge transfer. As a proof‐of‐concept, various metal–air batteries assembled with Fe‐ACSA@NC deliver remarkable power densities and capacities. This strategy is an effective and universal technique for electron modulation of M−N−C, which shows great potential in application of energy storage devices.
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Chen, Y., Ji, S., Wang, Y., Dong, J., Chen, W., Li, Z., Shen, R., Zheng, L., Zhuang, Z., Wang, D., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702473 · Cited by 1,988
Zhang, H., Hwang, S., Wang, M., Feng, Z., Karakalos, S., Luo, L., Qiao, Z., Xie, X., Wang, C., Su, D., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06514 · Cited by 1,526
Li, X., Huang, X., Xi, S., Miao, S., Ding, J., Cai, W., Liu, S., Yang, X., Yang, H., Gao, J., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b05992 · Cited by 1,466
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z.-L., Xu, D., Xu, J.-J., & Zhang, X.-B. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60248f · Cited by 1,447
Yuan, K., Lützenkirchen-Hecht, D., Li, L., Shuai, L., Li, Y., Cao, R., Qiu, M., Zhuang, X., Leung, M. K. H., Chen, Y., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b11852 · Cited by 1,047
Self-citationWavelet analysis of extended x-ray absorption fine structure data
Funke, H., Scheinost, A. C., & Chukalina, M. (2005) · Physical Review B · doi:10.1103/physrevb.71.094110 · Cited by 1,033
Advanced Electrocatalysts with Single-Metal-Atom Active Sites
Wang, Y., Su, H., He, Y., Li, L., Zhu, S., Shen, H., Xie, P., Fu, X., Zhou, G., Feng, C., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00594 · Cited by 1,005
Self-citationChen, Y., Ji, S., Zhao, S., Chen, W., Dong, J., Cheong, W.-C., Shen, R., Wen, X., Zheng, L., Rykov, A. I., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-07850-2 · Cited by 977
Shang, H., Zhou, X., Dong, J., Li, A., Zhao, X., Liu, Q., Lin, Y., Pei, J., Li, Z., Jiang, Z., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-16848-8 · Cited by 929
Review of Metal Catalysts for Oxygen Reduction Reaction: From Nanoscale Engineering to Atomic Design
Wang, X., Li, Z., Qu, Y., Yuan, T., Wang, W., Wu, Y., & Li, Y. (2019) · Chem · doi:10.1016/j.chempr.2019.03.002 · Cited by 876
Cited by
Hao, Y., Hung, S.-F., Zeng, W.-J., Wang, Y., Zhang, C., Kuo, C.-H., Wang, L., Zhao, S., Zhang, Y., Chen, H.-Y., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c07777 · Cited by 532
Self-citationZhang, T., Jin, J., Chen, J., Fang, Y., Han, X., Chen, J., Li, Y., Wang, Y., Liu, J., & Wang, L. (2022) · Nature Communications · doi:10.1038/s41467-022-34619-5 · Cited by 296
Lin, W., Zhu, M., Fan, Y., Wang, H., Tao, G., Ding, M., Liu, N., Yang, H., Wu, J., Fang, J., et al. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164163 · Cited by 64
Metadata
- Authors
- Huang, H., Yu, D., Hu, F., Huang, S., Song, J., Chen, H., Li, L. L., & Peng, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-01-31
- Volume
- 61
- Issue
- 12
- Pages
- e202116068-e202116068
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4200230004
- Cited by
- 434
- References
- 52
- FWCI
- 14.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Huang, H., Yu, D., Hu, F., Huang, S., Song, J., Chen, H., Li, L. L., & Peng, S. (2022). Clusters Induced Electron Redistribution to Tune Oxygen Reduction Activity of Transition Metal Single‐Atom for Metal–Air Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202116068
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