The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis
Abstract
The Fenton-like process presents one of the most promising strategies to generate reactive oxygen-containing radicals to deal with the ever-growing environmental pollution. However, developing improved catalysts with adequate activity and stability is still a long-term goal for practical application. Herein, we demonstrate single cobalt atoms anchored on porous N-doped graphene with dual reaction sites as highly reactive and stable Fenton-like catalysts for efficient catalytic oxidation of recalcitrant organics via activation of peroxymonosulfate (PMS). Our experiments and density functional theory (DFT) calculations show that the CoN 4 site with a single Co atom serves as the active site with optimal binding energy for PMS activation, while the adjacent pyrrolic N site adsorbs organic molecules. The dual reaction sites greatly reduce the migration distance of the active singlet oxygen produced from PMS activation and thus improve the Fenton-like catalytic performance.
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Cites
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
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Self-citationFei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Self-citationAtomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation
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Cited by
Edge-nitrogenated biochar for efficient peroxydisulfate activation: An electron transfer mechanism
Wang, H., Guo, W., Liu, B., Wu, Q., Luo, H., Zhao, Q., Si, Q., Sseguya, F., & Ren, N. (2019) · Water Research · doi:10.1016/j.watres.2019.05.059 · Cited by 914
Self-citationChen, F., Huang, G.-X., Yao, F.-B., Yang, Q., Zheng, Y.-M., Zhao, Q.-B., & Yu, H.-Q. (2020) · Water Research · doi:10.1016/j.watres.2020.115559 · Cited by 459
Zhao, S., Li, J., Wang, R., Cai, J., & Zang, S. (2022) · Advanced Materials · doi:10.1002/adma.202107291 · Cited by 270
Metadata
- Authors
- Li, X., Huang, X., Xi, S., Miao, S., Ding, J., Cai, W., Liu, S., Yang, X., Yang, H., Gao, J., Wang, J., Huang, Y., Zhang, T., & Liu, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-08-30
- Volume
- 140
- Issue
- 39
- Pages
- 12469-12475
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2888827392
- Cited by
- 1,466
- References
- 7
- FWCI
- 48.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, X., Huang, X., Xi, S., Miao, S., Ding, J., Cai, W., Liu, S., Yang, X., Yang, H., Gao, J., Wang, J., Huang, Y., Zhang, T., & Liu, B. (2018). Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b05992
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