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Bifunctional WC‐Supported RuO2 Nanoparticles for Robust Water Splitting in Acidic Media

Sun, Shu‐Chao, Jiang, Hao, Chen, Zi‐Yao, Chen, Qing, Ma, Ming‐Yuan, Zhen, Liang, Song, Bo, Xu, Cheng‐Yan·2022·Angewandte Chemie International Edition

Abstract

We report the strong catalyst–support interaction in WC‐supported RuO 2 nanoparticles (RuO 2‐WC NPs) anchored on carbon nanosheets with low loading of Ru (4.11 wt.%), which significantly promotes the oxygen evolution reaction activity with a η10 of 347 mV and a mass activity of 1430 A g Ru−1, eight‐fold higher than that of commercial RuO 2 (176 A g Ru−1). Theoretical calculations demonstrate that the strong catalyst–support interaction between RuO 2 and the WC support could optimize the surrounding electronic structure of Ru sites to reduce the reaction barrier. Considering the likewise excellent catalytic ability for hydrogen production, an acidic overall water splitting (OWS) electrolyzer with a good stability constructed by bifunctional RuO 2‐WC NPs only requires a cell voltage of 1.66 V to afford 10 mA cm−2. The unique 0D/2D nanoarchitectures rationally combining a WC support with precious metal oxides provides a promising strategy to tradeoff the high catalytic activity and low cost for acidic OWS applications.

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Metadata

Authors
Sun, S., Jiang, H., Chen, Z., Chen, Q., Ma, M., Zhen, L., Song, B., & Xu, C.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2022-03-23
Volume
61
Issue
21
Pages
e202202519-e202202519
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W4220679418
Cited by
214
References
9
FWCI
8.46
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Bifunctional WC‐Supported RuO2 Nanoparticles for Robust Water Splitting in Acidic Media. https://app.cochat.ai/papers/10.1002/anie.202202519
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Sun, S., Jiang, H., Chen, Z., Chen, Q., Ma, M., Zhen, L., Song, B., & Xu, C. (2022). Bifunctional WC‐Supported RuO2 Nanoparticles for Robust Water Splitting in Acidic Media. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202202519

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