The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate
Abstract
Electroreduction of CO 2 to acetate provides a promising strategy to reduce CO 2 emissions and store renewable energy, but acetate is usually a by‐product. Here, we show a stable and conductive two‐dimensional phthalocyanine‐based covalent‐organic framework (COF) as an electrocatalyst for reduction of CO 2 to acetate with a single‐product Faradaic efficiency (FE) of 90.3(2)% at −0.8 V (vs. RHE) and a current density of 12.5 mA cm−2 in 0.1 M KHCO 3 solution. No obvious degradation was observed over 80 hours of continuous operation. Combined with the comparison of the properties of other catalysts with isolated metal active sites, theoretical calculations and in situ infrared spectroscopy revealed that the isolated copper‐phthalocyanine active site with high electron density is conducive to the key step of C−C coupling of *CH 3 with CO 2 to produce acetate, and can avoid the coupling of *CO with *CO or *CHO to produce ethylene and ethanol.
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Cites
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
CO 2 electrolysis to multicarbon products in strong acid
Huang, J. E., Li, F., Ozden, A., Sedighian Rasouli, A., García de Arquer, F. P., Liu, S., Zhang, S., Luo, M., Wang, X., Lum, Y., et al. (2021) · Science · doi:10.1126/science.abg6582 · Cited by 1,359
Self-citationDopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Cited by
Chang, B., Pang, H., Raziq, F., Wang, S., Huang, K.-W., Ye, J., & Zhang, H. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00964e · Cited by 458
Microenvironment Engineering of Single/Dual‐Atom Catalysts for Electrocatalytic Application
Gao, Y., Liu, B., & Wang, D. (2023) · Advanced Materials · doi:10.1002/adma.202209654 · Cited by 319
Metadata
- Authors
- Qiu, X., Huang, J., Yu, C., Zhao, Z., Zhu, H., Ke, Z., Liao, P., & Chen, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-07-08
- Volume
- 61
- Issue
- 36
- Pages
- e202206470-e202206470
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4282834997
- Cited by
- 184
- References
- 5
- FWCI
- 7.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Qiu, X., Huang, J., Yu, C., Zhao, Z., Zhu, H., Ke, Z., Liao, P., & Chen, X. (2022). A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202206470
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