The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Ambient Electrosynthesis of Urea with Nitrate and Carbon Dioxide over Iron‐Based Dual‐Sites
Open accessAbstract
The development of efficient electrocatalysts to generate key *NH 2 and *CO intermediates is crucial for ambient urea electrosynthesis with nitrate (NO 3−) and carbon dioxide (CO 2). Here we report a liquid‐phase laser irradiation method to fabricate symbiotic graphitic carbon encapsulated amorphous iron and iron oxide nanoparticles on carbon nanotubes (Fe(a)@C‐Fe 3 O 4/CNTs). Fe(a)@C‐Fe 3 O 4/CNTs exhibits superior electrocatalytic activity toward urea synthesis using NO 3− and CO 2, affording a urea yield of 1341.3±112.6 μg h−1 mg cat−1 and a faradic efficiency of 16.5±6.1 % at ambient conditions. Both experimental and theoretical results indicate that the formed Fe(a)@C and Fe 3 O 4 on CNTs provide dual active sites for the adsorption and activation of NO 3− and CO 2, thus generating key *NH 2 and *CO intermediates with lower energy barriers for urea formation. This work would be helpful for design and development of high‐efficiency dual‐site electrocatalysts for ambient urea synthesis.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
A review on C1s XPS-spectra for some kinds of carbon materials
Chen, X., Wang, X., & Fang, D. (2020) · Fullerenes, Nanotubes and Carbon Nanostructures · doi:10.1080/1536383x.2020.1794851 · Cited by 1,748
Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst
Wu, Z.-Y., Karamad, M., Yong, X., Huang, Q., Cullen, D. A., Zhu, P., Xia, C., Xiao, Q., Shakouri, M., Chen, F.-Y., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-23115-x · Cited by 1,516
Wang, Y., Wang, C., Li, M., Yu, Y., & Zhang, B. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00116g · Cited by 1,313
Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters
Li, J., Zhan, G., Yang, J., Quan, F., Mao, C., Liu, Y., Wang, B., Lei, F., Li, L., Chan, A. W. M., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00418 · Cited by 1,108
Review of electrochemical ammonia production technologies and materials
Giddey, S., Badwal, S. P. S., & Kulkarni, A. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.09.054 · Cited by 886
Boosting Selective Nitrate Electroreduction to Ammonium by Constructing Oxygen Vacancies in TiO2
Jia, R., Wang, Y., Wang, C., Ling, Y., Yu, Y., & Zhang, B. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05260 · Cited by 863
Selective electrocatalytic synthesis of urea with nitrate and carbon dioxide
Lv, C., Zhong, L., Liu, H., Fang, Z., Yan, C., Chen, M., Kong, Y., Lee, C., Liu, D., Li, S., et al. (2021) · Nature Sustainability · doi:10.1038/s41893-021-00741-3 · Cited by 821
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Metadata
- Authors
- Geng, J., Ji, S., Jin, M., Zhang, C., Xu, M., Wang, G., Liang, C., & Zhang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2023-01-09
- Volume
- 62
- Issue
- 6
- Pages
- e202210958-e202210958
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4306913605
- Cited by
- 319
- References
- 45
- FWCI
- 12.05
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Geng, J., Ji, S., Jin, M., Zhang, C., Xu, M., Wang, G., Liang, C., & Zhang, H. (2023). Ambient Electrosynthesis of Urea with Nitrate and Carbon Dioxide over Iron‐Based Dual‐Sites. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202210958
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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