The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Halogen‐Incorporated Sn Catalysts for Selective Electrochemical CO2 Reduction to Formate
Abstract
Electrochemically reducing CO 2 to valuable fuels or feedstocks is recognized as a promising strategy to simultaneously tackle the crises of fossil fuel shortage and carbon emission. Sn‐based catalysts have been widely studied for electrochemical CO 2 reduction reaction (CO 2 RR) to make formic acid/formate, which unfortunately still suffer from low activity, selectivity and stability. In this work, halogen (F, Cl, Br or I) was introduced into the Sn catalyst by a facile hydrolysis method. The presence of halogen was confirmed by a collection of ex situ and in situ characterizations, which rendered a more positive valence state of Sn in halogen‐incorporated Sn catalyst as compared to unmodified Sn under cathodic potentials in CO 2 RR and therefore tuned the adsorption strength of the key intermediate (*OCHO) toward formate formation. As a result, the halogen‐incorporated Sn catalyst exhibited greatly enhanced catalytic performance in electrochemical CO 2 RR to produce formate.
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Cites
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationSingle-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation
Xiong, Y., Dong, J., Huang, Z.-Q., Xin, P., Chen, W., Wang, Y., Li, Z., Jin, Z., Xing, W., Zhuang, Z., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-020-0665-x · Cited by 610
Self-citationSulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate
Zheng, X., De Luna, P., García de Arquer, F. P., Zhang, B., Becknell, N., Ross, M. B., Li, Y., Banis, M. N., Li, Y., Liu, M., et al. (2017) · Joule · doi:10.1016/j.joule.2017.09.014 · Cited by 515
Wu, Z., Wu, H., Cai, W., Wen, Z., Jia, B., Wang, L., Jin, W., & Ma, T. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202102832 · Cited by 354
Cited by
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
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Metadata
- Authors
- Wang, T., Chen, J., Ren, X., Zhang, J., Ding, J., Liu, Y., Lim, K. H., Wang, J., Li, X., Yang, H., Huang, Y., Kawi, S., & Liu, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2023-01-24
- Volume
- 62
- Issue
- 10
- Pages
- e202211174-e202211174
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4312113956
- Cited by
- 169
- References
- 4
- FWCI
- 6.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, T., Chen, J., Ren, X., Zhang, J., Ding, J., Liu, Y., Lim, K. H., Wang, J., Li, X., Yang, H., Huang, Y., Kawi, S., & Liu, B. (2023). Halogen‐Incorporated Sn Catalysts for Selective Electrochemical CO2 Reduction to Formate. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202211174
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