2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications

Navarro‐Suárez, Adriana M.; Maleski, Kathleen; Makaryan, Taron; Yan, Jun; Anasori, Babak; Gogotsi, Yury

doi:10.1002/batt.201800014

Cited by 108MXene and MAX Phase MaterialsSupercapacitor Materials and FabricationElectrocatalysts for Energy Conversion

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2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications

Navarro‐Suárez, Adriana M., Maleski, Kathleen, Makaryan, Taron, Yan, Jun, Anasori, Babak, Gogotsi, Yury·2018·Batteries & Supercaps

DOI 10.1002/batt.201800014

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Abstract

Solution‐processable two‐dimensional (2D) materials offer the possibility of manufacturing heterostructures with various properties, creating a way to tune materials towards a specific application. Two different 2D materials, titanium carbide MXene (Ti 3 C 2 T x ) and reduced graphene oxide (rGO), have shown promising results for supercapacitor applications due to their flake‐like morphology, high conductivity; and ability to intercalate molecules or ions for charge storage. Here, we demonstrate the self‐assembly of a heterostructure between negatively charged Ti 3 C 2 T x and positively charged modified rGO after shear mixing. Changes in zeta ( ζ ) potential, X‐ray diffraction (XRD) patterns; and Raman spectra confirm the assembly of this heterostructure. The produced rGO : Ti 3 C 2 T x heterostructures were used as electrodes for supercapacitors. The addition of rGO to Ti 3 C 2 T x allowed some widening of the voltage window. Moreover, due to the synergistic effect of these materials, an increase of the capacitance value was observed. An electrode film composed of rGO (1 wt.%) and Ti 3 C 2 T x (99 wt.%) achieved capacitance values up to 254 F ⋅ g −1 at 2 mV ⋅ s −1 and 193 F ⋅ g −1 at 100 mV ⋅ s −1 .

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The shift of the MXene (002) peak to a larger angle after thermal reduction indicates re-stacking of the MXene sheets.
“indicating the re-stacking of the MXene sheets [30, 31]”
From Hybrid MXene/reduced graphene oxide aerogel microspheres for hydrogen evolution reaction (2021) · cites this paper as [30]

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Self-citation
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Influential
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Heterostructure Nanomaterials for Supercapacitor Applications
Kumar, N. S., & Naidu, K. C. (2020) · doi:10.1016/b978-0-12-819723-3.00010-x

Authors: Navarro‐Suárez, A. M., Maleski, K., Makaryan, T., Yan, J., Anasori, B., & Gogotsi, Y.
Affiliations: CIC energiGUNE (ES)
Drexel University (US)
Harbin Engineering University (CN)
Corresponding author: Gogotsi, Yury
ORCID: Navarro‐Suárez, Adriana M.
Maleski, Kathleen
Makaryan, Taron
Yan, Jun
Anasori, Babak
Gogotsi, Yury
Venue: Batteries & Supercaps
Publisher: Wiley
Published: 2018-04-20
Volume: 1
Issue: 1
Pages: 33-38
ISSN: 2566-6223 (ISSN-L)
DOI: 10.1002/batt.201800014
OpenAlex: W2802551710
Cited by: 108
References: 0
Citations by year: 2026: 9 · 2025: 13 · 2024: 15 · 2023: 9 · 2022: 12 · 2021: 21 · 2020: 16 · 2019: 12 · 2018: 1
FWCI: 4.66
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Batteries & Supercaps (publishedVersion)
Funders: CIC energiGUNE
Basque Government Scholarship for pre-doctoral formation (PRE_2015_2_0096)
Egonlabur Traveling Grant (EP_2016_1_0030)
Topics: Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: Ti3C2Tx MXene, reduced graphene oxide, heterostructures, supercapacitors, self-assembly, shear mixing, electrode materials, specific capacitance, voltage window, zeta potential, two-dimensional materials

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2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications

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