The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Molybdenum Sulfides and Selenides as Possible Electrocatalysts for CO 2 Reduction
Abstract
Linear scaling relations between reaction intermediates pose a fundamental limitation to the CO 2 reduction activity of transition‐metal catalysts. To design improved catalysts, we propose to break these scaling relations by binding key reaction intermediates to different sites. Using density functional theory, we demonstrate this principle in the active edge sites in MoS 2 , MoSe 2 , and Ni‐doped MoS 2 . These edges show the unique property of selectively binding COOH and CHO to bridging S or Se atoms and CO to the metal atom. DFT calculations suggest a significant improvement in CO 2 reduction activity over the transition metals. Our results point to the broader application of the active edge sites of transition‐metal dichalcogenides in complex electrochemical processes.
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“In particular, as in the free energy diagram shown in Fig. 4 in detail, the predicted theoretical limiting potential (U L) for CH3OH production using Pt@dv-Gr is significantly less negative than any catalysts that produce CH4 or CH3OH in the literature, synthesized (–0.5 to –1.0 V)35,37,38 or predicted (–0.3 V to –1.0 V).4,6,39,40”
From Single-atom catalysts for CO 2 electroreduction with significant activity and selectivity improvements (2017) · cites this paper as [40]
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Self-citationTrends in the exchange current for hydrogen evolution
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Self-citationIdentification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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Self-citationHow copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
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Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,321
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White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J. H., Yan, Y. S., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,698
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Materials for solar fuels and chemicals
Montoya, J. H., Seitz, L. C., Chakthranont, P., Vojvodić, A., Jaramillo, T. F., & Nørskov, J. K. (2016) · Nature Materials · doi:10.1038/nmat4778 · Cited by 1,589
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Metadata
- Authors
- Chan, K., Tsai, C., Hansen, H. A., & Nørskov, J. K.
- Affiliations
- Stanford University (US)
- SLAC National Accelerator Laboratory (US)
- Corresponding author
- Nørskov, Jens K.
- Venue
- ChemCatChem
- Publisher
- Wiley
- Published
- 2014-07
- Volume
- 6
- Issue
- 7
- Pages
- 1899-1905
- ISSN
- 1867-3880 (ISSN-L)
- 1867-3899
- OpenAlex
- W2023137992
- Cited by
- 311
- References
- 44
- Citations by year
- 2026: 16 · 2025: 16 · 2024: 23 · 2023: 29 · 2022: 36 · 2021: 36 · 2020: 32 · 2019: 40 · 2018: 27 · 2017: 17 · 2016: 18 · 2015: 13 · 2014: 7
- FWCI
- 6.05
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemCatChem (publishedVersion)
- Funders
- National Science Foundation
- Multidisciplinary University Research Initiative
- Air Force Office of Scientific Research
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- CO2 reduction, molybdenum sulfide, molybdenum selenide, transition metal dichalcogenides, edge sites, electrocatalysts, scaling laws, reaction intermediates
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