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Ionic Liquid Analogues Formed from Hydrated Metal Salts
Abstract
A dark green, viscous liquid can be formed by mixing choline chloride with chromium(III) chloride hexahydrate and the physical properties are characteristic of an ionic liquid. The eutectic composition is found to be 1:2 choline chloride/chromium chloride. The viscosity and conductivity are measured as a function of temperature and composition and explained in terms of the ion size and liquid void volume. The electrochemical response of the ionic liquid is also characterised and it is shown that chromium can be electrodeposited efficiently to yield a crack‐free deposit. This approach could circumvent the use of chromic acid for chromium electroplating, which would be a major environmental benefit. This method of using hydrated metal salts to form ionic liquids is shown to be valid for a variety of other salt mixtures with choline chloride.
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Abbott, A. P., Capper, G., Davies, D. L., Munro, H. L., Rasheed, R. K., & Tambyrajah, V. (2001) · Chemical Communications · doi:10.1039/b106357j · Cited by 1,100
Self-citation
Cited by
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Self-citationApplications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Self-citationLow-transition-temperature mixtures (LTTMs): A new generation of designer solvents
Francisco, M., van den Bruinhorst, A., & Kroon, M. C. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207548 · Cited by 1,378
Metadata
- Authors
- Abbott, A. P., Capper, G., Davies, D. L., & Rasheed, R. K.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2004-07-22
- Volume
- 10
- Issue
- 15
- Pages
- 3769-3774
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2052038370
- Cited by
- 431
- References
- 1
- FWCI
- 4.61
- Type
- journal article
- Language
- en
- Open access
- closed
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