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An Organocatalytic [3+2] Cyclisation Strategy for the Highly Enantioselective Synthesis of Spirooxindoles
Abstract
Power of P: Phosphine-promoted [3+2] annulation reactions between electron-poor allenes and 3-arylidene indolin-2-ones afford a new organocatalytic strategy for the synthesis of the spirocyclic core of oxindolic cyclopentanes (see scheme). Asymmetric variants of these reactions have been implemented by using chiral catalysts, giving very high levels of asymmetric induction.
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Potent and orally active small-molecule inhibitors of the MDM2-p53 interaction
Yu, S., Qin, D., Shangary, S., Chen, J., Wang, G., Ding, K., McEachern, D., Qiu, S., Nikolovska-Coleska, Z., Miller, R., et al. (2009) · Journal of Medicinal Chemistry · doi:10.1021/jm901400z · Cited by 180
Cited by
Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters
Xu, P.-W., Yu, J.-S., Chen, C., Cao, Z.-Y., Zhou, F., & Zhou, J. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03694 · Cited by 325
Gicquel, M., Gomez, C., Garcia Alvarez, M. C., Pamlard, O., Guérineau, V., Jacquet, E., Bignon, J., Voituriez, A., & Marinetti, A. (2018) · Journal of Medicinal Chemistry · doi:10.1021/acs.jmedchem.8b01137 · Cited by 34
Metadata
- Authors
- Voituriez, A., Pinto, N., Neel, M., Retailleau, P., & Marinetti, A.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2010-09-17
- Volume
- 16
- Issue
- 42
- Pages
- 12541-12544
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2165756524
- Cited by
- 210
- References
- 1
- FWCI
- 13.58
- Type
- journal article
- Language
- en
- Open access
- closed
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- Voituriez, A., Pinto, N., Neel, M., Retailleau, P., & Marinetti, A. (2010). An Organocatalytic [3+2] Cyclisation Strategy for the Highly Enantioselective Synthesis of Spirooxindoles. Chemistry – A European Journal. https://doi.org/10.1002/chem.201001791
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
