The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Restriction of Intramolecular Motions: The General Mechanism behind Aggregation‐Induced Emission
Abstract
Aggregation‐induced emission (AIE) has been harnessed in many systems through the principle of restriction of intramolecular rotations (RIR) based on mechanistic understanding from archetypal AIE molecules such as tetraphenylethene (TPE). However, as the family of AIE‐active molecules grows, the RIR model cannot fully explain some AIE phenomena. Here, we report a broadening of the AIE mechanism through analysis of 10,10′,11,11′‐tetrahydro‐5,5′‐bidibenzo[a,d][7]annulenylidene (THBDBA), and 5,5′‐bidibenzo[a,d][7]annulenylidene (BDBA). Analyses of the computational QM/MM model reveal that the novel mechanism behind the AIE of THBDBA and BDBA is the restriction of intramolecular vibration (RIV). A more generalized mechanistic understanding of AIE results by combining RIR and RIV into the principle of restriction of intramolecular motions (RIM).
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Citations
Cites
Fluorescent and luminescent probes for detection of reactive oxygen and nitrogen species
Chen, X., Tian, X., Shin, I., & Yoon, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15037e · Cited by 980
Cited by
Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Self-citationSupramolecular materials based on AIE luminogens (AIEgens): construction and applications
Li, J., Wang, J., Li, H., Song, N., Wang, D., & Tang, B. Z. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00495e · Cited by 741
Self-citationAggregate Science: From Structures to Properties
Zhang, H., Zhao, Z., Turley, A. T., Wang, L., McGonigal, P. R., Tu, Y., Li, Y., Wang, Z., Kwok, R. T. K., Lam, J. W. Y., et al. (2020) · Advanced Materials · doi:10.1002/adma.202001457 · Cited by 518
Self-citationZhang, Z., Fang, X., Liu, Z., Liu, H., Chen, D., He, S., Zheng, J., Yang, B., Qin, W., Zhang, X., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201914397 · Cited by 242
Peng, X.-L., Ruiz-Barragan, S., Li, Z.-S., Li, Q.-S., & Blancafort, L. (2016) · Journal of Materials Chemistry C · doi:10.1039/c5tc03322e · Cited by 181
Metadata
- Authors
- Leung, N. L. C., Xie, N., Yuan, W., Liu, Y., Wu, Q., Peng, Q., Miao, Q., Lam, J. W. Y., & Tang, B. Z.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2014-10-09
- Volume
- 20
- Issue
- 47
- Pages
- 15349-15353
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2167930632
- Cited by
- 794
- References
- 1
- FWCI
- 10.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Leung, N. L. C., Xie, N., Yuan, W., Liu, Y., Wu, Q., Peng, Q., Miao, Q., Lam, J. W. Y., & Tang, B. Z. (2014). Restriction of Intramolecular Motions: The General Mechanism behind Aggregation‐Induced Emission. Chemistry – A European Journal. https://doi.org/10.1002/chem.201403811
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