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Synthesis of Phosphorus‐Doped Graphene and its Wide Potential Window in Aqueous Supercapacitors
Abstract
Phosphorus‐doped (P‐doped) graphene with the P doping level of 1.30 at % was synthesized by annealing the mixture of graphene and phosphoric acid. The presence of P was confirmed by elemental mapping and X‐ray photoelectron spectroscopy, while the morphology of P‐doped graphene was revealed by using scanning electron microscopy and transmission electron microscopy. To investigate the effect of P doping, the electrochemical properties of P‐doped graphene were tested as a supercapacitor electrode in an aqueous electrolyte of 1 M H 2 SO 4. The results showed that doping of P in graphene exhibited significant improvement in terms of specific capacitance and cycling stability, compared with undoped graphene electrode. More interestingly, the P‐doped graphene electrode can survive at a wide voltage window of 1.7 V with only 3 % performance degradation after 5000 cycles at a current density of 5 A g−1, providing a high energy density of 11.64 Wh kg−1 and a high power density of 831 W kg−1.
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Cites
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Fine Structure Constant Defines Visual Transparency of Graphene
Nair, R. R., Blake, P., Grigorenko, A. N., Novoselov, K. S., Booth, T. J., Stauber, T., Peres, N. M. R., & Geim, A. K. (2008) · Science · doi:10.1126/science.1156965 · Cited by 9,084
Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618
Synthesis and applications of graphene-based noble metal nanostructures
Tan, C., Huang, X., & Zhang, H. (2013) · Materials Today · doi:10.1016/j.mattod.2013.01.021 · Cited by 286
Cited by
Wang, Y., Xiao, J., Wang, H., Zhang, T. C., & Yuan, S. (2022) · Journal of Materials Science & Technology · doi:10.1016/j.jmst.2021.05.035 · Cited by 113
Mirjalili, A., Dong, B., Pena, P., Ozkan, C. S., & Ozkan, M. (2020) · Energy Storage · doi:10.1002/est2.201 · Cited by 46
Metadata
- Authors
- Wen, Y., Wang, B., Huang, C., Wang, L., & Hulicova‐Jurcakova, D.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2014-11-07
- Volume
- 21
- Issue
- 1
- Pages
- 80-85
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2102739377
- Cited by
- 276
- References
- 4
- FWCI
- 7.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wen, Y., Wang, B., Huang, C., Wang, L., & Hulicova‐Jurcakova, D. (2015). Synthesis of Phosphorus‐Doped Graphene and its Wide Potential Window in Aqueous Supercapacitors. Chemistry – A European Journal. https://doi.org/10.1002/chem.201404779
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