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Cited by 288

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Recent Progress in Research on High‐Voltage Electrolytes for Lithium‐Ion Batteries

Tan, Shi, Ji, Ya J., Zhang, Zhong R., Yang, Yong·2014·ChemPhysChem

Abstract

Developing a stable and safe electrolyte that works at voltages as high as 5 V is a formidable challenge in present Li‐ion‐battery research because such high voltages are beyond the electrochemical stability of the conventional carbonate‐based solvents available. In the past few years, extensive efforts have been carried out by the research community toward the exploration of high‐voltage electrolytes. In this review, recent progress in the study of several promising high‐voltage electrolyte systems, as well as their recipes, electrochemical performance, electrode compatibility, and characterization methods, are summarized and reviewed. These new electrolyte systems include high‐voltage film‐forming additives and new solvents, such as sulfones, ionic liquids, nitriles, and fluorinated carbonates. It appears to be very difficult to find a good high‐voltage (∼5 V) electrolyte with a single‐component solvent at the present stage. Using mixed fluorinated–carbonate solvents and additives are two realistic solutions for practical applications in the near term, while sulfones, nitriles, ionic liquids and solid‐state electrolyte/polymer electrolytes are promising candidates for the next generation of high‐voltage electrolyte systems.

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Metadata

Authors
Tan, S., Ji, Y. J., Zhang, Z. R., & Yang, Y.
Venue
ChemPhysChem
Publisher
Wiley
Published
2014-07-14
Volume
15
Issue
10
Pages
1956-1969
ISSN
  • 1439-4235 (ISSN-L)
  • 1439-7641
OpenAlex
W2145196846
Cited by
288
References
98
FWCI
10.26
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Recent Progress in Research on High‐Voltage Electrolytes for Lithium‐Ion Batteries. https://app.cochat.ai/papers/10.1002/cphc.201402175
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Tan, S., Ji, Y. J., Zhang, Z. R., & Yang, Y. (2014). Recent Progress in Research on High‐Voltage Electrolytes for Lithium‐Ion Batteries. ChemPhysChem. https://doi.org/10.1002/cphc.201402175

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