The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Acid‐Catalyzed Conversion of Sugars and Furfurals in an Ionic‐Liquid Phase
Abstract
The reactivity of monosaccharides, furfural, and 5‐hydroxymethyl‐2‐furfural (HMF) in the presence of a Brønsted acid (added as H 2 SO 4) in the ionic liquid 1‐butyl‐3‐methylimidazolium chloride (BMImCl) is investigated at 120 °C. Fructose is converted much faster than mannose, glucose, and xylose and yields HMF with high selectivity, even in the absence of acid. Conversion of mannose, glucose, and xylose involves more complex reaction networks. Only small amounts of furfural and HMF are converted in the absence of other reactants but both compounds are consumed when monosaccharides and their degradation products are present. Acid‐catalyzed degradation reactions also lead to the formation of solid residues (humins).
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Cites
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Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
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Enhancement of cellulose saccharification kinetics using an ionic liquid pretreatment step
Dadi, A. P., Varanasi, S., & Schall, C. A. (2006) · Biotechnology and Bioengineering · doi:10.1002/bit.21047 · Cited by 574
Vanoye, L., Fanselow, M., Holbrey, J. D., Atkins, M. P., & Seddon, K. R. (2009) · Green Chemistry · doi:10.1039/b817882h · Cited by 158
Cited by
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
A review of ionic liquids: Applications towards catalytic organic transformations
Vekariya, R. L. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.11.123 · Cited by 1,021
Activation of Carbonyl-Containing Molecules with Solid Lewis Acids in Aqueous Media
Román-Leshkov, Y., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs200411d · Cited by 401
Gandini, A. (2010) · Polym. Chem. · doi:10.1039/b9py00233b · Cited by 295
Rinaldi, R., Meine, N., vom Stein, J., Palkovits, R., & Schüth, F. (2010) · ChemSusChem · doi:10.1002/cssc.200900281 · Cited by 201
Metadata
- Authors
- Sievers, C., Musin, I., Marzialetti, T., Valenzuela Olarte, M. B., Agrawal, P. K., & Jones, C. W.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2009-07-10
- Volume
- 2
- Issue
- 7
- Pages
- 665-671
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2073095158
- Cited by
- 255
- References
- 6
- FWCI
- 14.17
- Type
- journal article
- Language
- en
- Open access
- closed
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