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Zeolite‐Catalyzed Isomerization of Triose Sugars
Abstract
Zeozymes: Sn-Beta zeolite is found to be a highly active catalyst for the conversion of triose sugars. If the solvent is water, isomerization of the triose sugars takes place to form lactic acid in 90 % yield at 125 °C. If methanol is used as the solvent, an overall isomerization–esterification reaction takes place and methyl lactate is formed in quantitative yields at 80 °C. This represents one of the most selective zeolite-catalyzed biomass transformation reactions.
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Cited by
Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
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Román-Leshkov, Y., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs200411d · Cited by 401
Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries
Kohli, K., Prajapati, R., & Sharma, B. K. (2019) · Energies · doi:10.3390/en12020233 · Cited by 357
Čejka, J., Centi, G., Perez-Pariente, J., & Roth, W. J. (2012) · Catalysis Today · doi:10.1016/j.cattod.2011.10.006 · Cited by 312
Iglesias, J., Martínez-Salazar, I., Maireles-Torres, P., Martin Alonso, D., Mariscal, R., & López Granados, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00177e · Cited by 292
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
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Lin, L., Han, X., Han, B., & Yang, S. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00039j · Cited by 269
Chen, S. S., Maneerung, T., Tsang, D. C. W., Ok, Y. S., & Wang, C.-H. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.020 · Cited by 258
Schwartz, T. J., O’Neill, B. J., Shanks, B. H., & Dumesic, J. A. (2014) · ACS Catalysis · doi:10.1021/cs500364y · Cited by 175
Metadata
- Authors
- Taarning, E., Saravanamurugan, S., Spangsberg Holm, M., Xiong, J., West, R. M., & Christensen, C. H.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2009-07-10
- Volume
- 2
- Issue
- 7
- Pages
- 625-627
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2140518627
- Cited by
- 276
- References
- 0
- FWCI
- 8.15
- Type
- journal article
- Language
- en
- Open access
- closed
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