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High‐Surface‐Area Carbon Molecular Sieves for Selective CO2 Adsorption
Abstract
A series of carbon molecular sieves (CMSs) has been prepared, either as powders or monoliths, from petroleum pitch using potassium hydroxide as the activating agent. The CMS monoliths are prepared without the use of a binder based on the self‐sintering ability of the mesophase pitch. Characterization results show that these CMSs combine a large apparent surface area (up to ca. 3100 m 2 g−1) together with a well‐developed narrow microporosity (Vn up to ca. 1.4 cm 3 g−1). The materials exhibit high adsorption capacities for CO 2 at 1 bar and 273 K (up to ca. 380 mg CO 2 g sorbent−1). To our knowledge, this is the best result obtained for CO 2 adsorption using carbon‐based materials. Furthermore, although the CO 2 adsorption capacity for activated carbons has usually been considered lower than that of zeolites, the reported values exceed the total amount adsorbed on traditional 13X and 5A zeolites (ca. 230 mg and 180 mg CO 2 g sorbent−1, respectively), under identical experimental conditions. Additionally, the narrow pore openings found in the CMS samples (ca. 0.4 nm) allows for the selective adsorption of CO 2 from molecules of similar dimensions (e.g., CH 4 and N 2).
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Citations
Cites
Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
Choi, S., Drese, J. H., & Jones, C. W. (2009) · ChemSusChem · doi:10.1002/cssc.200900036 · Cited by 2,596
Karl, T. R., & Trenberth, K. E. (2003) · Science · doi:10.1126/science.1090228 · Cited by 2,070
The role of carbon materials in heterogeneous catalysis
Rodríguez-reinoso, F. (1998) · Carbon · doi:10.1016/s0008-6223(97)00173-5 · Cited by 1,760
Self-citationInterannual extremes in the rate of rise of atmospheric carbon dioxide since 1980
Keeling, C. D., Whorf, T. P., Wahlen, M., & van der Plichtt, J. (1995) · Nature · doi:10.1038/375666a0 · Cited by 1,345
Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures
Cavenati, S., Grande, C. A., & Rodrigues, A. E. (2004) · Journal of Chemical & Engineering Data · doi:10.1021/je0498917 · Cited by 1,147
Adsorption of CO2 on Molecular Sieves and Activated Carbon
Siriwardane, R. V., Shen, M.-S., Fisher, E. P., & Poston, J. A. (2001) · Energy & Fuels · doi:10.1021/ef000241s · Cited by 943
Yazaydın, A. Ö., Snurr, R. Q., Park, T.-H., Koh, K., Liu, J., LeVan, M. D., Benin, A. I., Jakubczak, P., Lanuza, M., Galloway, D. B., et al. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9057234 · Cited by 907
Amine-Grafted MCM-48 and Silica Xerogel as Superior Sorbents for Acidic Gas Removal from Natural Gas
Huang, H. Y., Yang, R. T., Chinn, D., & Munson, C. L. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020440u · Cited by 713
Yazaydın, A. Ö., Benin, A. I., Faheem, S. A., Jakubczak, P., Low, J. J., Willis, R. R., & Snurr, R. Q. (2009) · Chemistry of Materials · doi:10.1021/cm900049x · Cited by 588
Marsh, H., & Rodríguez-Reinoso, F. (2006) · Activated Carbon · doi:10.1016/b978-008044463-5/50016-9 · Cited by 509
Self-citationChue, K. T., Kim, J. N., Yoo, Y. J., Cho, S. H., & Yang, R. T. (1995) · Industrial & Engineering Chemistry Research · doi:10.1021/ie00041a020 · Cited by 499
Franchi, R. S., Harlick, P. J. E., & Sayari, A. (2005) · Industrial & Engineering Chemistry Research · doi:10.1021/ie0504194 · Cited by 400
Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification
Bae, Y.-S., Farha, O. K., Hupp, J. T., & Snurr, R. Q. (2009) · Journal of Materials Chemistry · doi:10.1039/b900390h · Cited by 392
Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
Bae, Y.-S., Farha, O. K., Spokoyny, A. M., Mirkin, C. A., Hupp, J. T., & Snurr, R. Q. (2008) · Chemical Communications · doi:10.1039/b805785k · Cited by 383
Kinetic separation of methane—carbon dioxide mixture by adsorption on molecular sieve carbon
Kapoor, A., & Yang, R. T. (1989) · Chemical Engineering Science · doi:10.1016/0009-2509(89)80014-4 · Cited by 237
Sorbents for CO2 capture from high carbon fly ashes
Mercedes Maroto-Valer, M., Lu, Z., Zhang, Y., & Tang, Z. (2008) · Waste Management · doi:10.1016/j.wasman.2007.10.012 · Cited by 189
Amine-Bearing Mesoporous Silica for CO2 and H2S Removal from Natural Gas and Biogas
Belmabkhout, Y., De Weireld, G., & Sayari, A. (2009) · Langmuir · doi:10.1021/la903238y · Cited by 180
Belmabkhout, Y., & Sayari, A. (2009) · Chemical Engineering Science · doi:10.1016/j.ces.2009.05.039 · Cited by 180
The combined use of different approaches in the characterization of microporous carbons
Rodríguez-Reinoso, F., Garrido, J., Martín-Martínez, J. M., Molina-Sabio, M., & Torregrosa, R. (1989) · Carbon · doi:10.1016/0008-6223(89)90153-x · Cited by 177
Self-citationNakagawa, Y., Molina‐Sabio, M., & Rodríguez-Reinoso, F. (2007) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.01.029 · Cited by 158
Self-citationSurface modification of low cost carbons for their application in the environmental protection
Arenillas, A., Rubiera, F., Parra, J. B., Ania, C. O., & Pis, J. J. (2005) · Applied Surface Science · doi:10.1016/j.apsusc.2005.02.076 · Cited by 148
Adsorption of CO2, CH4, and N2in Activated Carbon Honeycomb Monolith
Ribeiro, R. P. P. L., Pokrywiecki, T. S., Lopes, F. V. S., Moreira, R. D. F. P. M., Grande, C. A., & Rodrigues, A. E. (2008) · Journal of Chemical & Engineering Data · doi:10.1021/je800161m · Cited by 141
In situ nitrogen enriched carbon for carbon dioxide capture
Thote, J. A., Iyer, K. S., Chatti, R. V., Labhsetwar, N. K., Biniwale, R. B., & Rayalu, S. S. (2009) · Carbon · doi:10.1016/j.carbon.2009.09.042 · Cited by 139
Characterization of microporous solids by immersion calorimetry
Silvestre‐Albero, J. (2001) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/s0927-7757(01)00620-3 · Cited by 125
Self-citationEthanol removal using activated carbon: Effect of porous structure and surface chemistry
Silvestre‐Albero, A., Silvestre‐Albero, J., Sepúlveda‐Escribano, A., & Rodríguez-Reinoso, F. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.10.012 · Cited by 114
Self-citationRemoval and recovery of compressed CO2 from flue gas by a novel thermal swing chemisorption process
Lee, K. B., & Sircar, S. (2008) · AIChE Journal · doi:10.1002/aic.11531 · Cited by 85
Kinetic Restrictions in the Characterization of Narrow Microporosity in Carbon Materials
Rios, R. V. R. A., Silvestre‐Albero, J., Sepúlveda‐Escribano, A., Molina‐Sabio, M., & Rodríguez-Reinoso, F. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp0701486 · Cited by 71
Self-citationSilvestre‐Albero, A., Ramos-Fernández, J. M., Escandell, M. M., Sepúlveda‐Escribano, A., Silvestre‐Albero, J., & Rodríguez-Reinoso, F. (2009) · Carbon · doi:10.1016/j.carbon.2009.10.001 · Cited by 63
Self-citationProduction of binderless activated carbon monoliths by KOH activation of carbon mesophase materials
Ramos-Fernández, J. M., Escandell, M. M., & Rodríguez-Reinoso, F. (2007) · Carbon · doi:10.1016/j.carbon.2007.11.042 · Cited by 59
Self-citationGonzález, M. T., Sepúlveda‐Escribano, A., Molina‐Sabio, M., & Rodríguez-Reinoso, F. (1995) · Langmuir · doi:10.1021/la00006a050 · Cited by 50
Self-citationNew acrylic monolithic carbon molecular sieves for O2/N2 and CO2/CH4 separations
Nabais, J. M. V., Carrott, P. J. M., Carrott, M. M. L. R., Padre-Eterno, A., Menéndez, J. Á., Dominguez, A., & Ortiz, Á. L. (2005) · Carbon · doi:10.1016/j.carbon.2005.11.005 · Cited by 39
Preparation of carbon molecular sieves by controlled oxidation treatments
Gómez-de-Salazar, C., Sepúlveda‐Escribano, A., & Rodríguez-Reinoso, F. (2000) · Carbon · doi:10.1016/s0008-6223(00)00138-x · Cited by 30
Self-citation
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Sustainable porous carbons with a superior performance for CO2 capture
Sevilla, M., & Fuertes, A. B. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00784f · Cited by 1,088
N‐Doped Polypyrrole‐Based Porous Carbons for CO2 Capture
Sevilla, M., Valle‐Vigón, P., & Fuertes, A. B. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201100291 · Cited by 936
Metal‐Free Carbon Materials for CO2 Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754
Hedin, N., Andersson, L., Bergström, L., & Yan, J. (2013) · Applied Energy · doi:10.1016/j.apenergy.2012.11.034 · Cited by 424
Importance of small micropores in CO 2 capture by phenolic resin-based activated carbon spheres
Wickramaratne, N. P., & Jaroniec, M. (2013) · J. Mater. Chem. A · doi:10.1039/c2ta00388k · Cited by 415
Metadata
- Authors
- Wahby, A., Ramos‐Fernández, J. M., Martínez‐Escandell, M., Sepúlveda‐Escribano, A., Silvestre‐Albero, J., & Rodríguez‐Reinoso, F.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2010-06-28
- Volume
- 3
- Issue
- 8
- Pages
- 974-981
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2150021001
- Cited by
- 353
- References
- 32
- FWCI
- 40.76
- Type
- journal article
- Language
- en
- Open access
- closed
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